Page 195 - Microsensors, MEMS and Smart Devices - Gardner Varadhan and Awadelkarim
P. 195

INTRODUCTION     175

                      P  M  M M                    P*M
                     M  M   M  M         hv              M
                    M  p  M   P  M               M  p  M   P* M
                     M  M  P M  M    Actinic photons  M  M  P*M  M
                         M  M        from  UV  source  M  M
                      P = Photoinitiator         Photoinitiator excitation
                      M =  monomer


                       P-M»  M  M                   P-M  MM
                      M    P<S                     M M   P* M  M
                        M    M»M
                     M  p  M   P  M               M  p  M   P  M
                                                   M  M  P-M  M
                         M  M                          M  M
                      Chain initiation           Free-radical  generation



                       P-M--M'
                           p
                     ^M  X  yi                           P > M
                     M         P                  M      M   P
                       P- > M
                      Chain propagation           Chain termination (—)

       Figure 7.3  Example  of  a simplified free-radical  photopolymerisation  sequence  used  in  MSL




                             Intensity  j/    \
                    Light     1       /         \
                                                    -
                    source          /            \   Gaussian beam
                                   fS              V.
                                — •-
                                                   1

                                                      Cured  spot
                    Resist






     Figure 7.4  Theoretical  intensity profile of  the  UV  beam  (Gaussian)  and the  resultant  spot  cured
     within  the photoresist


       The  fraction  of  light  transmitted  through  an  absorbing  system  is  given  by  the
     Beer-Lambert  law  (see for example, Wayne (1998)):


                                      = exp(—aCd)
                                  7 t// 0                                  (7.1)
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