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50    MEMS MATERIALS AND THEIR PREPARATION

                  Table  3.4  The atomic  properties  and crystal  structures of selected
                  metals
                  Atomic     Symbol  Atomic radius  Lattice  Interatomic
                  number (Z)             (A)      structure  distance (A)
                     13        Al         .43     FCC         2.86
                     22        Ti         .47     HCP         2.90
                     24        Cr         .25     BCC  (a)    2.49
                                          .36     HCP  (ß)    2.71
                     26        Fe         .24     BCC  (a)    2.48
                                          .26     FCC (y)     2.52
                     27        Co         .25     HCP  (a)    2.49
                                          .26     FCC  (ß)    2.51
                     28        Ni         .25     HCP  (a)    2.49
                                          .25     FCC  (ß)    2.49
                     29        Cu         .28     FCC         2.55
                     30        Zn         .33     HCP         2.66
                     47        Ag         .44     FCC         2.97
                     78        Pt         .38     FCC         2.77
                     79        Au         .44     FCC         2.88
                     82        Pb         .75     FCC         3.49


        Metals  are,  in  general,  good  thermal  and  electrical  conductors.  They  are  somewhat
      strong  and  ductile  at  room  temperature  and  maintain  good  strength  both  at  room  and
      elevated  temperatures.  Table F.1 in Appendix F gives  some important physical  properties
      of  metals  that are  commonly used  in  microelectronics  and MEMS.
        Table  3.4 provides atomic and crystal structure information on  12 selected  metals,  and
      these illustrate  the  three principal  lattice  structures described  earlier.


      3.2.2  Metallisation

      Metallisation  is a process  in which metal films are  formed on the  surface  of a  substrate.
                                                                         5
      These  metallic  films  are  used  for  interconnections,  ohmic  contacts,  and  so  on .  Metal
      films  can  be  formed  using  various  methods,  the  most  important  being  physical  vapour
      deposition  (PVD).  PVD  is  performed  under vacuum  using  either  the  evaporation  or  the
      sputtering technique.


      3.2.2.1  Evaporation

      Thin  metallic  films  can  be  evaporated  from  a  hot  source  onto  a  substrate,  as  shown in
      Figure  3.17.  An evaporation  system consists  of a vacuum chamber,  pump, wafer  holder,
      crucible,  and  a  shutter.  A  sample  of  the  metal  to  be  deposited  is  placed  in  an  inert
      crucible,  and the  chamber  is  evacuated  to a pressure  of  10 -6  to  10 -7  torr. The crucible
      is then heated  using a tungsten filament or an electron  beam to flash-evaporate the  metal
      from  the crucible  and condense  it onto the cold  sample.  The film thickness  is determined

      5
       Copper-based  printed circuit board  and other  interconnect  technologies  are discussed  in Section  4.5.
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