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APPLICATIONS                                    20 ELECTRICAL CONDUCTIVE CNT DISPERSED Si N CERAMICS
                                                                                                  3  4

                              With CNT                            Without CNT

















                                                            No CNTs
                                                           1.8wt%CNT
                              6    5   4    3   2    1   0          0      1      2     3      4
                                                                                     -12
                                                                                        3
                                                  3
                                               -12
                                    Wear volume (10 m )                   Wear volume (10 m )
                                    Si N  disc                            SUJ2 ball
                                     3 4
                  Figure 20.4
                  Wear property of CNT dispersed Si N ceramics.
                                             4
                                            3
                  Consequently, electrical conductivity and superior             References
                  mechanical properties can be achieved simultane-
                  ously by adding  Y O –Al O –TiO –AlN to Si N .  [1] C.L. Xu, B.Q. Wei, R.Z. Ma, J. Liang, X.K. Ma and
                                                            4
                                          3
                                                         3
                                        2
                                  2
                                    3
                                               2
                  The electroconductivity of the HIPped sample was   D.H. Wu: Carbon, 37(5), 855–858 (1999).
                  30  S/m.  Therefore, electrical property improved  [2] J. Sandler, M.S.P. Shaffer,  T. Prasse,  W. Bauhofer,
                  without degradation of mechanical properties.      K. Schulte and  A.H.  Windle:  Polymer,  40(21),
                  Hotpressed sample had higher electrical and        5967–5971(1999).
                  mechanical properties than HIPped sample.  These  [3] G.-D. Zhan, J.D. Kuntz, J. Wan and A.K. Mukherjee:
                  electroconductive Si N ceramics can be applied in  Nat. Mater., 2, 38–42 (2003).
                                     4
                                   3
                  extremely severe  mechanical and environmental  [4] A. Peigney, C. Laurent, E. Flahaut and A. Rousset:
                  conditions such as ceramic bearings for high-speed,  Ceram. Int., 26, 677–683 (2000).
                  high-temperature, high-corrosion and high-vacuum  [5] Ch. Laurent,  A. Peigney, O. Dumortier and
                  environments, and as novel functional materials
                  with high durability and electrical conductivity,  A. Rousset: J. Eur. Ceram. Soc., 18, 2005–2013 (1998).
                  which result from achievement of densification at  [6] J.  Tatami, M.  Toyama, K. Noguchi, K. Komeya,
                  lower temperature. Furthermore, as a result of ball-  T. Meguro and M. Komatsu:  Key Eng. Mater.,  247,
                  on-disk test for wear properties, it was confirmed  83–86 (2003).
                  that wear volume of not only Si N itself but   [7] J. Tatami, T. Katashima, K. Komeya, T. Meguro and
                                                3
                                                   4
                  also SUJ2 mating metallic material decreased       T. Wakihara: J. Am. Ceram. Soc., 88, 2889–2893 (2005).
                  (Fig. 20.4).                                   [8] S. Hampshire and K.H. Jack: in: Progress in Nitrogen
                    Si N ceramics was applied to bearing materials   Ceramics, F.L. Riley (Ed.), Martinus Nijhoff, Boston,
                     3
                       4
                  with longer lifetime and higher reliability to replace  p. 263 (1983).
                  metallic materials. The developed electroconductive  [9] H. Wada.,  M.J. Wang  and T.Y. Tien:  J. Am.  Ceram.
                  Si N ceramics with high strength, toughness and
                    3
                      4
                  wear resistance can restrict degradation of system  Soc., 71, 837–840 (1988).
                  lifetime due to dust adhesion. For this reason, they are  [10] Cs. Balázsi, F.S. Cinar, O.  Addemir, F.  Wéber and
                  expected to be applied as bearing materials for the  P. Arató: J. Eur. Ceram. Soc., 24 (12), 3287–3294 (2004).
                  electronic components and so on for which the con-  [11] Cs. Balázsi, Z. Kónya, F.  Wéber, L.P. Biró and
                  ventional one cannot be used.                      P. Arató: Mater. Sci. Eng. C, 23, 1133–1137 (2003).
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