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Source: Photodetection and Measurement

                                                                                      Chapter
                                                                                       9








                      Contamination and Industrial Systems












           9.1 Introduction

                       The multibeam referencing and intensity compensation configurations intro-
                       duced in the last chapter are of enormous help with another problem that affects
                       the long-term stability of an optical measurement. In this Chapter we will think
                       about some of the problems involved in transferring a high performance optical
                       instrument, well designed in consideration of photon budgets and temperature
                       drift performance, to an industrial environment where it is up against a differ-
                       ent set of stresses, the greatest of which is so called fouling. This is the inevitable
                       contamination that builds up on the optical surfaces and windows of an instru-
                       ment in service. Several of the techniques presented here are related to those
                       used for stability improvement in Chap. 8, although the emphasis is more on
                       environmental effects rather than temperature variations. We will look at some
                       real measurement problems, and the designs of a few instruments which have
                       been used successfully in difficult industrial sensing applications.


           9.2 Transfer to the Industrial Arena
                       Large numbers of optical sensors used for industrial diagnostics and control
                       systems operate on-line (i.e., a sample of fluid is brought to the instrument in
                       dedicated pipe-work) or even in-line (where the sensor is immersed in a flowing
                       process fluid stream or installed in a section of process piping). In both cases
                       the optoelectronic elements, sources and detectors, are separated from the fluid
                       by robust transparent windows, for instance of plastic, glass, fused-quartz
                       (amorphous SiO 2) or sapphire (single-crystal Al 2O 3). Although it is often
                       assumed that the window is just a passive, protecting interface between sample
                       and sensor, over time it can become a significant variable element in its own
                       right. In particular, windows can become coated with chemical deposits, often
                       aided by biological films. As the fouling layer builds up, optical transmission
                       decreases and fluorescence can increase, leading to measurement errors.

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