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the
                                                                       as  binder
                                                                       black  sodium


                                                           n             conductive
                                                     O
         e −                    e −                ONa        PF-COONa  acetylene  conductive
                       Broken  electric contacts  Keep  electric contacts  ONa  O  Conductive binder  using approaches  binder,  of Synthetic






                   e −                    e −         1.TFA, rt, overnight  2.Na 2 CO 3  n  Traditional  nonconductive  and  (C)  cycles.
             Delithiation          Delithiation    O  O       PF-COOBu  (A)  additive



                                                   O                       charge/discharge
                                                      O           Nonconductive binder  materials.  conductive
                                              N-type conductive binder  Pd(PPh 3 ) 4 , K 2 CO 3  85°C, 72 h  battery  in  issue  Replacing  repeated  during Reproduced with permission from Liu D, Zhao Y, Tan R, Tian L-L, Liu Y, Chen H, et al. Novel conductive binder for high-performance silicon anodes  Elsevier.  2017










                                                      O  O  B  O       change  (B)  electrode  Copyright
                                                   O          M2       volume  binder.  the  PF-COONa.
             First lithiation  Chemical bonds  First lithiation  O  O  O  B  O  Conductive additive  address  to  mechanical  as  of integrity  acid),  2017;36:206–12.





         Traditional method  Non-conductive binder  This work  Nonconductive binder  O  O  O  +  Br  M1  Silicon particles  approaches  the  of  polymer nonconductive  mechanical  and  Energy  Nano








                        (A)                   (B)     O   Br  (C)      Schematics  and  electric  the poly(3,3 0 -(9H-fluorene-9,9-diyl)dipropionic  batteries.  ion


                                                                       10.8  conductive  keep  lithium
                                                                       Fig.  could  in
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