Page 83 - Principles of Catalyst Development
P. 83
70 CHAPTER 4
TABLE 4.8. Catalytic Activity of Transition Metal Oxides and Sulfides
Group Element Compound Reaction
--------~"'.
IB Cli CuO Oxidation of Co, hydrocarbons
nitric oxide
CuCr20~ Hydrogenation of nitro aromatic
aromatic carbonyls,
aromatic olefins,
unsaturated nitriles
Decarboxylation of acids
Synthesis of pyrazines
Decomposition of perchloric acid
AgO
Au 2O,
VIII, Ni NiO Dehydrogenation of alkanes
Oxidation of hydrocarbons
VII I, CO CoO Hydrogenation of olefins
VIII, Fe Fe J 0 4 Water gas shift
Dehydrogenation of cyclohexanes
Conversion of alcohols to amines
VIIB Mn Mn02 Oxidation of alcohols
Dehydrogenation of ketones
Hydration of nitrites
VlB Cr Cr,o., Cyclization of C 3 to C, paraffins
Mo MoO, Dehydrogenation of cyclohexanes
Dehydration of aliphatic alcohols
Oxidation of propylene
Polymerization of olefins
Disproportionation of olefins
Oxidation of CH,OH to CH 20
MoS, Water gas shift
Hydrogenolysis of C-S, C- N, C-O
W Wo., Disproportionation of olefins
Dehydration of alcohols
Cyclization of C, to C 5 paraffins
WS, Hydrogenolysis of C-S, C- N, C-O
VB V V,O, Oxidation of hydrocarbons
Butene to maleic anhydride
Benzene to pthalic anhydride
Cyclization of C, to (', paraffins
IVB Ti TiO, Photocatalytic decomposition of water