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The Crystal Lattice System










                Figure 2.7. Silicon nitride appears
                in many crystalline configurations.
                             α
                The structure of   and of β
                Si N 4   are based on vertical
                  3
                stacks of SiN 4   tetrahedra, as
                shown in (I) and (II) respectively.  (I)                    (II)



                             whose constituents are taken from the columns III and V of the periodic
                             table. The atoms form into a zinc-blende crystal, structurally similar to
                             the diamond-like structure of silicon, but with gallium and arsenic atoms
                             alternating, see Figure 2.8.














                Figure 2.8. The zinc-blende struc-
                ture of gallium arsenide. The two
                atom types are represented by
                spheres of differing diameter. Also
                see Figure 2.2.






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