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                 294   Mechanical Engineering Design
                                          Corrosion
                                          It is to be expected that parts that operate in a corrosive atmosphere will have a lowered
                                          fatigue resistance. This is, of course, true, and it is due to the roughening or pitting of
                                          the surface by the corrosive material. But the problem is not so simple as the one of
                                          finding the endurance limit of a specimen that has been corroded. The reason for this is
                                          that the corrosion and the stressing occur at the same time. Basically, this means that in
                                          time any part will fail when subjected to repeated stressing in a corrosive atmosphere.
                                          There is no fatigue limit. Thus the designer’s problem is to attempt to minimize the fac-
                                          tors that affect the fatigue life; these are:
                                          • Mean or static stress
                                          • Alternating stress
                                          • Electrolyte concentration
                                          • Dissolved oxygen in electrolyte
                                          • Material properties and composition
                                          • Temperature
                                          • Cyclic frequency
                                          • Fluid flow rate around specimen
                                          • Local crevices


                                          Electrolytic Plating
                                          Metallic coatings, such as chromium plating, nickel plating, or cadmium plating, reduce
                                          the endurance limit by as much as 50 percent. In some cases the reduction by coatings
                                          has been so severe that it has been necessary to eliminate the plating process. Zinc
                                          plating does not affect the fatigue strength. Anodic oxidation of light alloys reduces
                                          bending endurance limits by as much as 39 percent but has no effect on the torsional
                                          endurance limit.


                                          Metal Spraying
                                          Metal spraying results in surface imperfections that can initiate cracks. Limited tests
                                          show reductions of 14 percent in the fatigue strength.

                                          Cyclic Frequency
                                          If, for any reason, the fatigue process becomes time-dependent, then it also becomes
                                          frequency-dependent. Under normal conditions, fatigue failure is independent of fre-
                                          quency. But when corrosion or high temperatures, or both, are encountered, the cyclic
                                          rate becomes important. The slower the frequency and the higher the temperature, the
                                          higher the crack propagation rate and the shorter the life at a given stress level.


                                          Frettage Corrosion
                                          The phenomenon of frettage corrosion is the result of microscopic motions of tightly
                                          fitting parts or structures. Bolted joints, bearing-race fits, wheel hubs, and any set of
                                          tightly fitted parts are examples. The process involves surface discoloration, pitting, and
                                          eventual fatigue. The frettage factor k f depends upon the material of the mating pairs
                                          and ranges from 0.24 to 0.90.
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