Page 43 - The Petroleum System From Source to Trap
P. 43

,  . .



                                                            2.  Petroleum System Logic as an Exploration Tool   35
                                                    .
                                                   .         Table 2.1 .  OCS Sale 57-Norton Basin COST Well Shows
                     COST                      COST
                     N0. 1                      N 0 . 2       Depth  (ft)                Shows
               SL                                            Cost-1
                                                             1 0 ,200            Streaming cut fluorescence
                                SEISMIC                      10,250             Cut fluorescence
                                EVENTS            .          1 0 ,91 0           Crush  cut fluorescence
                                                             1 0 ,960-1 0,990 (core)   Patchy stain  and cut fluorescence
                                                             Cost-2
                                                    .. .     1 1   ,825-1 1 ,830   Trace free oil  in  mud
                                                .  .  .  .  .
                                                 .  .  ..  ..  .  .
                                                                2
                                                •  •  •  . 41.11 11   12, 1 o -1 2,220   Major gas show
                                                .  .    ·-�- .  .
                                                ·:·:·;�-�-·-:·:   1 2 ,1 90-14,500   Gas shows  in several sandstones
                                                � ::,
                                                · · · • ···•···
                                                  '  ,
                                                   )
                                                   :
                                                :· :  �:::·�·                     indicated by mud  gas  unit and
                                                                                  by neutron-density wireline logs
                                                  '
                                                ' ' ·· ' ' ·'
                                                  .�:�: ·: �·:  .
                                                 •  ¥"•  •  •  •
                                                ·.·�·-,\':.
                                                             concept  was  that  even  if these  coals  contained  lipid
                                                   i .·
                                                    .·
                                                 • .·  . , .  • .·  .  • .·  . . . .     material,  most  of the oil would  have  been  lost  prior  to
                                                    i (t  .·
                                                             deposition of the basin fill sequence. Thus,  this  show did
                                                   .
                                                    -        not  enhance  the  oil potential  of  the  Stuart  subbasin  in
                                                             Shell's interpretation .
                                                  ...   • . .
                                                                Rock-Eval Pyrolysis Evidence
                                                                An indication of when enough oil has been generated
                                                             to  allow  oil  expulsion  can be  derived  from  Rock-Eval
                                                             pyrolysis  data.  The  Rock-Eval  instrument  measures  the
                                    REO                       amount  of  hydrocarbons  evolved  from a sample as the
                                                             sample temperature is increased from room temperature
                                                              to 500'C.  The oil-like hydrocarbons evolved below 300'C
                                                              were  present  in  the  sample at the  start  of  the  analysis,
                                                              and  their  total  amount  is reported  as  the  S1  peak.  The
                 1 4                                          magnitude of the S1  peak  is a measure of the oil content
                                                              of the  sample.  The  hydrocarbons  evolved  above  300'C
                 1 5                                          are largely formed by pyrolysis of kerogen in the sample.
                   TO 1 4 ,693               TO  1 4 ,889     The  total  amount  of  these  hydrocarbons  formed  by
                                                              pyrolysis is  reported  as  the  S2  peak and  represents  the
                                                              remaining  hydrocarbon-generating  potential  of the
                                  SEAL ROCK                   sample.
                                                                While  the  thermal  maturity  of  a  source  rock  is
                             .. . . .                         increasing and  oil is being  generated, the  value  of
                               .
                             ,-·:·;_·_  .
                              ·
                             -:�:-�:·:   RESERVOIR            S1 /TOC  increases  until  oil expulsion  starts.  After  oil
                                   ROCK                       expulsion begins, the value of S1/TOC remains approxi­
                                                              mately  constant  over  a  limited  depth  interval  and  then
                                   LOW PERM                   decreases  with  increasing depth  and  thermal  maturity.
                                   BEDS
                                                              For  the  cases  we  have  studied,  S1 /TOC  must  attain a
                                                              value in the range of 0.1-0.2 for oil expulsion to start.
                                                                Figure  2.17 shows  the  plot  of S1 /TOC  versus  depth
            Figure 2.16. Stratigraphy of the COST ·1 and COST -2 wells
            of the Norton basin.                              for samples from the two COST wells. Recall that in these
                                                              wells,  oil  generation  is  expected  to  be  significant  at  a
                                                              depth of about 9000 ft and to continue to about 12,000 ft.
            However, the observation of some free oil in the mud at   The values  of StfTOC  for  the  COST-2  sidewall  core
            11,825-11,830 ft demonstrates that some oil was expelled   samples are low throughout.  There is  little  indication of
            in  the  COST -2  well.  The  significance  of  this  show  is   significant  oil  generation  from  9000  to  10,500  ft.  Even  at
            discussed in the next section.                    12,000 ft  where  oil  generation  is  expected  to  be  essen­
              Robertson Research (U.S.) reported an oil show below   tially complete, S1 /TOC  is only  about  0.04 compared to
            the  red  unconformity  at  12,240  ft  in  the  COST-2  well   about  0.1  required  for  the  onset  of oil  expulsion.  We
            based  on  a  rock extract.  This  oil show occurred  close to   interpret these results to mean that the intervals sampled
            the major gas show observed on the mud log (Table 2.1).   in COST"2  below  9000 ft are  not capable of expelling oil
            Both of these  shows  occurred  below  the  red  unconfor­  at any  thermal maturity level.  At high thermal maturity
            mity  and  are  believed  to be  derived  from  coals.  Shell's   (in  the  gas  window),  some  liquids  might  be  expelled
   38   39   40   41   42   43   44   45   46   47   48