Page 302 - Thermodynamics of Biochemical Reactions

302 Mathematica Solutions to Problems

Reaction 1

-19.9564 -21.1455 -24.8972 -31.3157 -37.3892
-18.0757 -19.82 -24.6736 -30.4846 -36.2155
-17.4137 -19.4683 -24.4199 -30.1133 -35.8228
6
3134.61 5064.24 23002.6 306367. 3.55032 10
6
1467.94 2966.78 21018.9 219099. 2.21129 10
6
1123.89 2574.39 18973.7 188625. 1.88735 10
-0.177235 -0.336077 -0.992429 -1.12833 -1.02082
-0.122329 -0.579942 -1.01164 -1.00952 -1.0011
-0.139449 -0.649491 -0.984363 -1.0005 -1.00008

This program produces three tables. The top table gives the standard transformed reaction Gibbs energies at three ionic
strengths and five pH values. The second table gives the corresponding equilibrium constants, and the third table gives the
changes in the binding of hydrogen ions.

Reaction 2

3.9532 3.72567 3.2948 3.15854 3.14189
3.89797 3.5248 3.20516 3.147 3.14071
3.86839 3.45934 3.18839 3.1451 3.14051

0.202971 0.222482 0.264715 0.279673 0.281558
0.207543 0.24126 0.274463 0.280978 0.281693
0.210035 0.247715 0.276326 0.281193 0.281714
-0.0141959 -0.0733161 -0.0509985 -0.00731544 -0.000761426
-0.0330731 -0.0847485 -0.0242531 -0.00280164 -0.000284407
-0.0419873 -0.080239 -0.0183996 -0.00204602 -0.000206853

Reaction 3

-12.5514 -13,7161 -17.4527 -23.8749 -29.9491
-12.258 -15.6976 -21.884 -27.9151 -33.6694
-12.3548 -16.9525 -23.2451 -29.1287 -34.858
158.085 252.901 1141.72 15229.1 176534.
140.444 562.446 6821.56 77710.5 791752.
6
146.033 933.1 11812.6 126794. 1.27886 10
-0.175363 -0.330035 -0.993053 -1.12864 -1.02085
-0.260983 -0.95943 -1.10486 -1.01996 -1.00216
-0.410005 -1.08946 -1.06644 -1.00934 -1.00097
Reaction 4

rxthermntab[fructosel6~hos+de==dihydroxyacetonephos+glyceraldehydeghos,~5,6,7,8,9},{O,.
1, -2511