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CHAPTER 5





                                           Gold-Aluminum



                                               Intermetallic


                                         Compounds and



                                            Other Metallic


                                  Interface Reactions



                                          in Wire Bonding







         5.1  Gold-Aluminum Intermetallic Compound Formation
               and Classical Wire-Bond Failures


              5.1.1 Introduction
              Gold-aluminum intermetallic compound formation and associated
              Kirkendall voids have resulted in more documented wire-bond fail-
              ures than any other problem over the years. There have been hun-
              dreds of papers on this subject, and this chapter can only present an
              overview of them. Modern packaging and device environments do
              not (or need not) involve the high temperatures (≥ 300°C) that pro-
              duced most of the classical failures. The compounds are typically
              referred to as “purple plague (the Al-rich phase).” This term comes
              from the characteristic color of the AuAl  intermetallic compound
                                                  2
              that often occurs around the perimeter of an Au bond on an Al pad.
              (Such colored intermetallic compounds are quite commonly found in
              metallurgy, and, as an example, Au and In also form a purple-colored
              intermetallic compound.) Most present day Au-Al related failures are



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