Page 1162 - Advanced Organic Chemistry Part A - Structure and Mechanisms, 5th ed (2007) - Carey _ Sundberg

c. 1147
O O PROBLEMS
) CO H + CH (CH ) OH
(CH 2 6 2 3 2 7 hv 350 nm (CH ) CO H
2 6
2
benzophenone
CH(CH ) CH 3
2 6
OH
d.
CH 3 CH 3
CH 3 CD 3 CD 3 CH 3 CH 3 CD 3 CH
hv + 3
> 290 nm
O O
O
CD group is equally distributed
3
between the exo and endo positions
e.
O
O
hv OCH 3
CH 3 CH
CH OH 3
3
CH 3 CH 3
f.

O O CH 3 O
CH 3 hv CH 3
CH 3 > 290 nm
CH 3
CH 3 H + CH 3 CH 3
CH 3 product in the
absence of acid

g.
H D
CH CD 2
hv D
H
CH CD 2 D D

h.
hv

i.
O O

hv
benzophenone