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2. Properties of Semiconductors for Solar Cells  11




                  N D is the donor concentration and N A , is the acceptor concentration. The conductiv-
                  ity increases by increasing the doping of semiconductor according to Eqs. (1.2a)
                  and (1.2b).

                  2.3 THE SEMICONDUCTOR CURRENTS

                  If a voltage V is applied across a semiconductor bar with length L and cross-sectional
                  area A, a current will flow in the bar because of the drift of electrons and holes under
                  the influence of the electric field E developed by the voltage V in the bar as shown in
                  Fig. 1.8.
                     This current follows the ohm’s law for relatively small electric fields, i.e.,
                                                        V


                                       I ¼ qA m n þ m p    hAJ d                 (1.3)
                                                    p
                                              n
                                                        L
                  where
                                                          V
                                           J d ¼ sE and E ¼
                                                          L
                  J d is the drift current density. The mobility m is the ability of the mobile charges to
                  acquire drift velocities in the presence of the electric field.
                     Another type of current exists in a semiconductor when concentration differ-
                  ences of mobile changes are present. Such current is termed the diffusion current
                  J dif . This current can be expressed by
                                               vn
                                      J ndif ¼ qD n  for electrons; and         (1.4a)
                                               vx
                                                    vp
                                         J pdif ¼ qD p  for holes               (1.4b)
                                                    vx
                  where D n and D p are the diffusion coefficients for electrons and holes, respectively,
                  and  vn  and  vp  are the concentration gradients for electrons and holes, respectively.
                     vx    vx
                  The diffusion coefficient D is related to the mobility by the Einstein equation
                                                 k B T
                                            D ¼ m    ¼ mV T                      (1.5)
                                                  q











                  FIGURE 1.8
                  A drift current I in a semiconductor by applying voltage V.
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