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                       82                        Applied Process Design for Chemical and Petrochemical Plants

                                           Table 10-13
                         Suggested Fouling Factors in Petrochemical Processes
                                                2
                                        r   (hr) (ft ) (°F)/Btu
                                                         Temperature Range
                       Fluid              Velocity, Ft/Sec   100°F   100°F

                       Waters:
                         Sea (limited to 125°F max.)   4  0.002    0.003
                                               7      0.0015       0.002
                         River (settled)       2       0.002     0.002—0.003
                                               4    0.0005—0.0015  0.001—0.0025
                         River (treated and settled)   2  0.0015   0.002
                                               4       0.001       0.0015
                       4 mils baked phenolic coating 65      0.0005           Fouling Factor, hr-ft 2 -°F/Btu                                             Fouling Factor
                       15 mils vinyl-aluminum coating        0.001
                       Condensate (100°—300°F)   2     0.001     0.002—0.0004
                                               4      0.0005       0.001
                       Steam (saturated) oil free               0.0005—0.0015
                         with traces oil                         0.001—0.002
                        ethylene, propylene, butane-clean) }
                       Light hydrocarbon liquids
                        (methane, ethane, propane,

                       Light hydrocarbon vapors: (clean)     0.001
                       Chlorinated hydrocarbons
                        (carbon tetrachloride,
                        chloroform, ethylene dichloride,
                        etc.)
                         Liquid                        0.001       0.002
                         Condensing                    0.001       0.0015
                         Boiling                       0.002       0.002
                       Refrigerants (vapor condensing
                        and liquid cooling)
                         Ammonia                             0.001
                         Propylene                           0.001
                         Chloro-fluoro-refrigerants          0.001           Figure 10-40A.  Fouling factors as a function of temperature and
                       Caustic liquid, salt-free                             velocity. (Used by permission: W. L. Nelson, No. 94 in series, Oil and
                         20% (steel tube)     3—8            0.0005          Gas Journal. ©PennWell Publishing Company.)
                         50% (nickel tube)    6—9            0.001
                         73% (nickel tube)    6—9            0.001
                       Gases (industrially clean)
                         Air (atmos.)                      0.0005—0.001      reasonable starting point. It is not wise to keep adjusting the
                         Air (compressed)                    0.001           estimated (or other) fouling to achieve a specific overall
                         Flue gases                        0.001—0.003       heat transfer coefficient, U, which is the next topic to be dis-
                         Nitrogen                            0.0005
                                                                             cussed.
                         Hydrogen                            0.0005
                                                                               Fouling generally can be kept to a minimum provided
                         Hydrogen (saturated with water)     0.002
                       Polymerizable vapors with inhibitor  0.003—0.03       that proper and consistent cleaning of the surface takes
                       High temperature cracking or                          place. Kern 269  discusses fouling limits. Inside tubes may be
                        coking, polymer buildup             0.02—0.06        rodded, brushed, or chemically cleaned, and most outside
                       Salt brines
                                                                             tube surfaces in a shell can be cleaned only by chemical or
                        (125°F max.)           2       0.003       0.004
                                                                             by hydraulic/corncob external cleaning or rodding/
                                               4       0.002       0.003
                       Carbon dioxide 93                                     brushing between tube lanes provided that the shell is
                        (sublimed at low temp.)              0.2—0.3         removable as in Figures 10-1A, 10-1B, 10-1D—F, 10-1I, and
                                                                             10-1K.
                                                                               Unless a manufacturer/fabricator is guaranteeing the per-
                         In the tables the representative or typical fouling resis-  formance of an exchanger in a specific process service, they
                       tances are referenced to the surface of the exchanger on  cannot and most likely will not accept responsibility for the
                       which the fouling occurs—that is, the inside or outside  fouling effects on the heat transfer surface. Therefore, the
                       tubes. Unless specific plant/equipment data represents the  owner must expect to specify a value to use in the thermal
                       fouling in question, the estimates in the listed tables are a  design of the equipment. This value must be determined
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