Page 480 - Battery Reference Book
P. 480

Types of constant-current  charging  47/13

     Table 47.3  Comparison of maximum charge rates in normal and continuous (float) charging at various temperatures recommended for
     SAFT VB series sealed nickel-cadmium  button cells
     Cell type                                   VB 4     VB 10    VB 22     VB 30    VB 40

     Rated capacity (Ah)                         40       100      220      300       600
     Nominal  discharge voltage per cell (V)      1.20      1.20     1.20     1.20     1.20
     Normal charge from -30  to +lO"C,   -30  (100)   0.4   1  .o    2.2      3.0      6.0
     max. charge rates (mA) for charge time   -20  (55)   0.8   2.0   4.0     6.0     12.0
     (h) in brackets                 -10  (30)    1.5      4.0       8.0     11.0     21 .0
                                       0 (20)     2.5      6.0      13.0     18.0     36.0
                                     +10  (14)    4.0      10.0     22.0     30.0     60.0
     Continuous charge from -30  to +lO"C,   -30  (100)   0.2   0.5   1.0     1.5      3 .0
     ma. charge rates (mA) for charge time   -20  (55)   0.4   1 .0   2.0     3.0      6.0
     (h) in brackets                 -10  (30)    0.8      2.0       4.0      5.0     11.0
                                       0 (20)     1.2      3.0       6.5      9.0     18.0
                                     +10  (14)    2.0      5.0      11.0     15.0     30.0

     Occasional overcharge at these rates beyond the prescribed times is  not  detrimental to  the cell. Rapid and ultra-rapid charge systems can be
     obtained for charging in times from a few seconds to  1 h


        1.6                                      and on permanent overcharge. A number of  methods
      -  1.5                         2.5 mA at 0 OC   are used  to  vary  the  charge current as  a function of
                                                 temperature:
      2  1.4
      m                                    ooc      Fit into the battery a temperature sensor that oper-
      z i.3
      >  1.2 t                                      ates on the charger to  adjust the charge current to
                                                    suit the battery temperature.
        1.1 1   I   I   I   1    I   I    i         Charge at  constant current  and  voltage  limited to
          0   8    16   24   32   40   48   56      1.55 Vkell, a voltage setting that will avoid all risk
                   Capacity charged EmA h)          of internal overpressure at low temperature.
                         (a)
                                                    Use the charge current corresponding to the lowest
          r                          13 rnA at 0 "C   operating temperature.
        1.5                                        Also, in certain cases, for example when charging
      u&e=                                 0 OC
      2  1.4                                     at low temperatures, constant-current charging can be
      0)
        1.:
      2 1.3                      I               combined with voltage limitation. With a normal char-
        1.2 i-                                   state  is  reached  after  14-16h  at  room  temperature.
      5
      5                                          ging current of  approximately 0.1C A a fully charged
        1.1 I   L  I    I   I    I   I    I      A lower current, 0.04-0.05C  A, is often used as con-
          Cl   44   88   132   176   220   264  308   tinuous charging current in different applications. The
                   Capacity charged (mA h)       charging efficiency is then lower, because proportion-
                         (b)                     ally more energy is used to produce oxygen. The char-
        1.6                                      ging efficiency is also dependent on the temperature,
     -  1.5                                      and decreases with rising temperature.
      >
     - 1.4
      m
     z 1.3                                       47.3.7  Permanent or floating
     >                                           constant-current charging
        1.2
                                                 In  applications with  permanent charge, the  object of
          0   120  240   360   480  600   720  840   the  charge  current  is  to  maintain  an  already  fully
                  Capacity charged IinA h)
                                                 charged nickel-cadmium  battery in  this  state over  a
                         (C)
                                                 period  of  time  and  when  necessary  to  recharge  any
     Figure 47.12 Voltage  versus  capacity  for  'normal'  charging  of   capacity discharged at regular intervals or in a random
     SAFT  VB  series  sealed  nickel-cadmium  button  cells.  (a) UB4   manner. The first charge may  be  carried out either at
     40Cs mh h; (b) UBZ 220C5 rnA h; (c) VB60 600C5 mA h (Courtesy   the permanent rate if this is sufficient (>O.O2C5 A), or
     of SAFT)
                                                 at a higher rate where the permanent charge value is
   475   476   477   478   479   480   481   482   483   484   485