Page 334 - Biodegradable Polyesters
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312  12  Biodegradable Polyesters Polymer–Polymer Composites

                                       Aluminium plates                  Teflon sheets

                     Spacers
                    PLLA/PGA
                    wire
                    (a)

                                                                            Quench to
                                                                              room
                                                                            temperature
                                                                             between
                                                                            aluminium
                       Heated platens                                        blocks
                       T = 185 °C




                    (b)                                  (c)







                    (d)
                    Figure 12.8 Cross section of layup of a  aluminum blocks at room temperature to
                    plate wound with PLLA/PGA filament before  quench the film (c). The process results in
                    compression molding (a). Hot pressing pro-  transformation of the drawn wire into a uni-
                    cedure (b). Quenching of film between two  form film (d).















                    Figure 12.9 PLLA/PGA MFC film.


                    of 1–2 μm. The higher PGA content of PLLA/PGA (70/30 by wt%) resulted
                    in more frequent occurrence of clusters of PGA particle in close proximity.
                    The MFCs resulting from cold-drawing and subsequent compression molding
                    of the PLLA/PGA blends were fractured parallel to the fibril direction – the
                    resulting surfaces are shown in Figure 12.10c,d. PLLA/PGA MFC (80/20 by
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