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HYDC01  12/5/05  5:44 PM  Page 9






                                                                                          Introduction  9


                   Table 1.2 Agents of material transport to the oceans. After Garrels et al. (1975).

                   Agent        % of total transport  Remarks
                   Rivers       89             Dissolved load 17%, suspended load 72%
                   Glacier ice   7             Ground rock debris plus material up to boulder size. Mainly from Antarctica
                                               and Greenland. Distributed in seas by icebergs
                   Groundwater   2             Dissolved materials similar to river composition. Estimate poorly constrained
                   Coastal erosion  1          Sediments eroded from cliffs, etc.
                   Volcanic      0.3(?)        Dust from explosive eruptions. Estimate poorly constrained
                   Wind-blown dust  0.2        Related to desert source areas and wind patterns, e.g. Sahara, major source for tropical Atlantic





                           6
                                                                                           3 −1
                               3 −1
                   (0.037 × 10 km a ) gives an average time that a  discharge to the oceans of 2220 km a , the average
                                                                                                      −1
                   water molecule spends in the ocean of about 37,000  dissolved solids concentration is about 585 mg L .
                   years. Lakes, rivers, glaciers and shallow ground-  This calculation illustrates the long residence time of
                   water have residence times ranging between days  groundwater in the Earth’s crust where its mineral
                   and thousands of years. Because of extreme variabil-  content is concentrated by dissolution.
                   ity in volumes and precipitation and evaporation
                   rates, no simple average residence time can be given
                   for each of these reservoirs. As a rough calculation,  1.6 Groundwater as a natural resource
                   and with reference to Fig. 1.5 and Table 1.1, if about
                             3 −1
                   6% (2220 km a ) of runoff from land is taken as  Groundwater is an important natural resource.
                   active groundwater circulation, then the time taken  Worldwide, more than 2 billion people depend on
                                                 3
                                              6
                   to replenish the volume (4.2 × 10 km ) of shallow  groundwater for their daily supply (Kemper 2004).
                   groundwater stored below the Earth’s surface is of  A large proportion of the world’s agriculture and irri-
                   the order of 2000 years. In reality, groundwater resid-  gation is dependent on groundwater, as are a large
                   ence times vary from about 2 weeks to 10,000 years  number of industries. Whether groundwater or sur-
                   (Nace 1971), and longer (Edmunds 2001). A similar  face water is exploited for water supply is largely
                   estimation for rivers provides a value of about 20  dependent on the location of aquifers relative to the
                   days. These estimates, although a gross simplification  point of demand. A large urban population with a
                   of the natural variability, do serve to emphasize the  high demand for water would only be able to exploit
                   potential longevity of groundwater pollution com-  groundwater if the aquifer, typically a sedimentary
                   pared to more rapid flushing of contaminants from  rock, has favourable storage and transmission proper-
                   river systems.                              ties, whereas in a sparsely populated rural district
                     As an agent of material transport to the oceans   more limited but essential water supplies might be
                   of products of weathering processes, groundwater  found in poor aquifers, such as weathered basement
                   probably represents only a small fraction of the total  rock.
                   transport (Table 1.2). Rivers (89% of total transport)  The relationship between population and geology
                   represent an important pathway while groundwater  can be inferred from Tables 1.3 and 1.4, which give a
                   accounts for a poorly constrained estimate of 2%   breakdown of water use by purpose and type (surface
                   of total transport in the form of dissolved materials  water and groundwater) for regions of England and
                   (Garrels et al. 1975). More recent estimates by  Wales. Surface water abstraction for electricity gen-
                   Zektser and Loáiciga (1993) indicate that globally the  eration is the largest category, but most of the fresh-
                   transport of salts via direct groundwater discharge is  water abstracted for cooling purposes is returned to
                                     9
                                        −1
                   approximately 1.3 × 10 ta , roughly equal to half   rivers and can be used again downstream. In terms  of
                   of the quantity contributed by rivers to the oceans.  public water supply abstractions, groundwater is espe-
                   Given a volumetric rate of direct groundwater   cially significant in the Southern (73% dependence
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