Page 178 - Introduction to Mineral Exploration
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8: EXPLORATION GEOCHEMISTRY  161



                   H                                                                               He

                   Li  Be                                                   B   C    N    O    F   Ne

                   Na Mg                                                   Al   Si   P    S   Cl   Ar

                   K   Ca Sc     Ti   V   Cr Mn Fe Co        Ni Cu Zn Ga Ge As Se             Br   Kr
                                                        Co
                                                        Rh
                   Rb Sr     Y   Zr Nb Mo Tc        Ru Rh Pd Ag Cd         In   Sn Sb     Te   I   Xe
                   Cs Ba La      Hf   Ta  W    Re Os     Ir Ir  Pt  Au Hg   Tl  Pb   Bi  Po   At   Rn

                   Fr  Ra Ac


                                 Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu

                                 Th Pa     U


                             Neutron activation analysis           Inductively coupled mass spectrometry
                             X-ray fluorescence                     Fire assay preconcentration various finishes

                             Atomic absorption spectrophotometry   Other methods
                             Inductively coupled emission spectrometry

                 FIG. 8.3  Summary periodic table showing cost-effective methods of elemental analysis at levels encountered
                 in background exploration samples.



                 TABLE 8.3 Summary of the main methods used in exploration geochemistry.
                 Method           Capital cost $  Multielement  Precision  Sample type  Cost per  comments sample
                                  (approx.)                          ($US)
                 Colorimetry        8000       No          Poor      Solution   2–10     Good for field use
                                                                                         and W, Mo
                 Atomic absorption  60,000     No          Good      Solution   1–5      Cheap and precise
                 spectrophotometry
                 X-ray fluorescence  200,000    Yes         Good      Solid      20       Good for
                                                                                         refractory
                                                                                         elements
                 ICP–ES           150,000      Yes         Good      Solution   10       Good for
                                                                                         transition metals
                 ICP–MS           150,000–     Yes         Good      Solution   10       Good for heavy
                                  1000,000                                               metals. High
                                                                                         resolution
                                                                                         instruments very
                                                                                         low detection
                                                                                         limits
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