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CMP: Chemical–Mechanical Polishing 169



           modification of the oxide: leaching of oxide by the slurry                 R
           softens the top layer, and the mechanical abrasion rate
           goes up.
             CMP slurries etch without mechanical polishing, just  t 2     q              h
           like fluorine etches silicon without plasma; but in both
           etching and CMP, it is the interaction between different  t 1
           processes that leads to the desired total process: slurry
           etch rates of 10 nm/min are typical, but CMP removal  Figure 16.7 Planarization relaxation distance R
           rates of 500 nm/min are standard.
                                                         Polishing rate and planarization rate are two different
                                                       concepts. Polishing rate is applicable to one material.
           16.4 APPLICATIONS OF CMP
                                                       Planarization rate is the rate of decrease in step height:
           Conformal deposition processes replicate the underlying  the high peaks are polished, which decreases step height,
           topography dutifully. Such processes are useful in gap  but some material is removed from the valleys too,
           filling: small spaces between lines are completely filled  which decreases the planarization rate. Towards the end
           without any voids. However, this argument does not  of the process, the planarization rate drops to zero, even
           hold for larger linewidths: step height is unchanged after  though the overall polishing rate is still finite.
           conformal deposition, as shown in Figure 16.6(a).  Selectivity in CMP bears close resemblance to
             Some deposited CVD films flow, or have flow-  etching: we need to know the polish rates of the top and
           like profiles, resulting in profiles like the one shown  bottom films in order to calculate, for instance, substrate
           in Figure 16.6(b). Spin-on dielectrics flow over the  loss during overpolishing. Identically to etching, it is
           topography, but the planarization length (Figure 16.7)  sometimes beneficial to have the same 1:1 selectivity
           defined as                                   between films, but, most often, it is desirable to remove
                           R = h/ tan θ         (16.4)  one film relatively rapidly, and to have high selectivity
                                                       against the bottom film, which can then be processed in
           is in the range of micrometres or tens of micrometres in  a separate step.
           the maximum, as shown in Figure 16.6(c). CMP is the  Oxide polishing is the oldest and most widely prac-
           closest you can get to global planarity.    ticed CMP process. Its main application is planarization
                                                       in multi-level metallization in advanced ICs, where it
                                                       provides a planar surface that makes subsequent lithog-
                                                       raphy and deposition steps easy. One problem with oxide
                                                       polishing is the lack of endpoint: there is no clear end for
                                                       polishing. This is called blind polishing. The opposite is
                              (a)
                                                       stopped polishing, in which, for instance, a nitride layer
                                                       acts as a polish stop (cf. etch-stop layer) but selectivities
                                                       are not necessarily very high.
                                                         Tungsten polishing is another CMP process that was
                                                       adopted rapidly. Contact holes and via holes are filled
                              (b)
                                                       by CVD tungsten, which is then removed from planar
                                                       areas, leaving just the contact plug filled with metal
                                                       (Figure 16.1(c)). The same structure can, of course, be
                                                       obtained by tungsten etchback, and the first implemen-
                                                       tations of tungsten plug process did use etchback. CMP
                              (c)
                                                       has proven to be better with respect to plug loss: at etch-
                                                       ing end point, the etchable area decreases dramatically
                                                       and the etchant will attack the tungsten in the plug, lead-
                                                       ing to severe plug recess. CMP is much better in this
                              (d)                      respect, but, naturally, process optimization with either
           Figure 16.6 Planarity: (a) conformal deposition, no pla-  technology can bring about improvements.
           narization; (b) surface smoothing during deposition; (c)  CMP is used whenever global planarity is required. In
           local planarization by spin-film and (d) global planarization  addition to multi-level metallization for ICs, other appli-
           by CMP                                      cations have sprung up. In superconducting quantum
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