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Questions and Problems  •  97

                                 heat-treated so as to become crystalline in nature. The following concept map notes
                                 this relationship:
                                                                                  Structure of glass–ceramics
                             Structure of                 Structure of
              Glass–Ceramics   noncrystalline solids        silica glasses          (fine-grained,
                 (Structure)                                                        polycrystalline)
                               (Chapter 3)                  (Chapter 12)
                                                                                    (Chapter 13)

















                                                                                                      m
                                                                                                   0.5
                                                                                                   0.5 
m
              Important Terms and Concepts
              allotropy                           crystal structure                lattice
              amorphous                           crystal system                   lattice parameters
              anisotropy                          diffraction                      Miller indices
              atomic packing factor (APF)         face-centered cubic (FCC)        noncrystalline
              body-centered cubic (BCC)           grain                            polycrystalline
              Bragg’s law                         grain boundary                   polymorphism
              coordination number                 hexagonal close-packed (HCP)     single crystal
              crystalline                         isotropic                        unit cell

              REFERENCES

              Buerger, M. J., Elementary Crystallography, Wiley, New York,   Hammond, C., The Basics of Crystallography and Diffraction,
                 NY, 1956.                                       3rd edition, Oxford University Press, New York, NY,
              Cullity, B. D., and S. R. Stock, Elements of X-Ray Diffraction,   2009.
                 3rd edition, Prentice Hall, Upper Saddle River, NJ, 2001.  Massa, W., Crystal Structure Determination,  Springer, New
              DeGraef, M., and M. E. McHenry, Structure of Materials: An  York, NY, 2004.
                 Introduction to Crystallography, Diffraction, and Symmetry,   Sands, D. E., Introduction to Crystallography, Dover, Mineola,
                 Cambridge University Press, New York, NY, 2007.  NY, 1975.

              QUESTIONS AND PROBLEMS

                Problem available (at instructor’s discretion) in WileyPLUS
              Fundamental Concepts                          3.3  Show for the body-centered cubic crystal struc-
              3.1  What is the difference between atomic structure   ture that the unit cell edge length a and the atomic
                 and crystal structure?                         radius R are related through a = 4R> 13.
                                                            3.4  For the HCP crystal structure, show that the ideal
              Unit Cells                                        c/a ratio is 1.633.
              Metallic Crystal Structures
                                                            3.5  Show that the atomic packing factor for BCC is
              3.2  If the atomic radius of lead is 0.175 nm, calculate   0.68.
                 the volume of its unit cell in cubic meters.
                                                            3.6  Show that the atomic packing factor for HCP is 0.74.
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