Page 377 - Book Hosokawa Nanoparticle Technology Handbook
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6.4 ELECTRIC PROPERTIES                                                      FUNDAMENTALS

                          Electrode  Sample    Electrode
                                                                                Ammeter
                                                                                 I
                         I                                                  r 1  a  r 2  g
                                                                  Voltmeter  V                 Power supply
                                         d                                            l
                                                                              b
                                  w
                                              l

                                          V                          (b) Three-probe method (g : guard eletrode)
                                                                                        2
                                                                        	 = R (A/l),  A = 
 (r +r ) /4
                                                                                       2
                                                                                     1
                        (a) Two-probe method    	 = R (A/l)
                                       V
                                                                        C         D
                                                     I
                                                                         w    l
                                                                   A                      B



                                            l                    (d) Four-probe method   = R (w/l)
                                                                    for thin films   	 s
                               A
                           (c) Four-probe method  	 = R (A/l)    D           C
                                                 V
                                         D
                                                  C              A           B
                                                                      (a)          (b)

                                              B
                                 A
                                             Power
                                       A
                                             supply
                                                                      (c)          (d)
                           (e) Van der Pauw method I               (f) Van der Pauw method II
                  Figure 6.4.9
                  Measurement methods for resistivity ( ) and sheet resistance (  ). R: electrical resistance between electrodes (voltage
                                                                s
                  V/current I), A: electrode area ( wd), l: distance between electrodes, w and d: width and length of an electrode.

                    6.4.2.3 Associate current measurement        where  j  and    are the imaginary number unit and
                  The contributions of different resistances, such as  angle frequency, respectively. The real part Z  and the
                                                                                                  2
                                                                                              2 2
                  resistances at the grain interior and grain boundary,  imaginary part Z  are Z   R/(1   R C ) and Z
                                                                              2
                                                                           2 2
                                                                   2
                  can be separated by complex impedance measure-   R C/(1   R C ), respectively; thus, the relation-
                  ment. In the case of a parallel circuit with the compo-  ship between Z  and Z  can be expressed by
                  nent resistance R and the component capacitance C,
                  the complex impedance Z (Z   Z –jZ ) is expressed by              2          2
                                                                            ⎛    R ⎞        ⎛ ⎞
                                                                                             R
                                                                                         2
                                                                            ⎜  ′ Z    ⎟     Z ′′    ⎜ ⎟  (6.4.9)

                                                                                             2
                                Z   1     R  1    j C,  (6.4.8)             ⎝     2 ⎠       ⎝ ⎠
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