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Modeling ideas I 131275
                both of these “systems” are employed, the spill quantity to be   of the former, the greater the protection offered by secondary
                used in the model is 2000 bbl - [1/2 x (3000 bbl)] + (3000 -   containment, the smaller the spill size to be used in modeling
                2000) = 1500 bbl. If the first spill volume is 4500 bbl, then the   spill consequences:
                model value is 2000 - [ 112 x (4500 bbl)] + (4500 - 2000) = 2000
                bbl (since the primary score should not be worsened by this exer-   Spill size reduction percentage = [(secondary containment Oh)
                cise). The value of 50% is rather arbitrary-as  is the mathemati-   (adjustment factor)]
                cal relationship used-and   can be  replaced  by  any value  or   where
                scoring approach more suitable to the evaluator. Consistency is
                more critical than the absolute value, in this case. Recall that   Secondary containment  YO =portion of  total  facility volume
                “penalties,” in  the  form  of  increased surface area, are  also   that can be held
                assigned to portions of the facility that are hidden from view   Adjustment factor   = obtained by adding all conditions
                (buried) and therefore have less opportunity for leak detection   that apply to the secondary con-
                by some methods.                                             tainment, up to the value of the
                 Added to the detection time is the reaction time, which is   secondary  containment  YO, as
                generally defined as the amount of additional time that will   showninTable 13.8. Inthis table,
                probably elapse between the strong leak indication and the iso-   items  are  detractors  from  sec-
                lation of the leaking facility (including drain downtime). Here,   ondary  containment  effective-
                consideration is given to automatic operations, remote opera-   ness, except the first.
               tions, proximity of shutdown devices, etc. As a simple way to
                account for various reaction times in the aforementioned scor-   Limited secondary containments such as pump seal vessels and
                ing protocols, the following rationale can be used: A spill vol-   sumps are designed to capture specific leaks.  As such they pro-
               ume equal to (a leak rate of 1000 gal/day) x (the most probable   vide risk reduction for only a limited range of scenarios. Risk
                reaction time) is added to the original spill volume. Benefits of   reduction credit can be given for secondary containment pro-
               remote and automatic operations as well as staffing levels are   portional to the size of the effective area it protects. Using this
                captured here.                             approach in one recent application, the credit was capped at a
                 This  is  thought to  fairly represent  the  value  of  reaction   maximum of go%,  regardless of the mathematical results, as
                time. Of course, for a large leak, this value is probably under-   shown inTable 13.9.
                stated and for a small leak it is probably overstated, but, over
                the  range of model uses and for a relative assessment, this
                approach  might  be  appropriate.  In  one  application  of  a   V.  Modeling ideas I
               methodology similar to the one  outlined here,  a sensitivity
                analysis showed that changes in leak detection and reaction   Dow Chemical Company’s Fire and Explosion Index [26] is a
                capabilities from 5,000 to  10,000 gallons changed the spill   well-regarded loss estimation system for process plants. It is an
               score and also the overall risk by 2 to 3%. This seemed reason-   indexing type assessment used for estimating the damage that
                able for the resolution level of that risk assessment. In a situa-   would probably result from an incident in a chemical process
               tion where the spill score is less dominated by the leak-volume   plant. The F&EI system is not designed for public safety evalu-
               component of the calculation and/or where the range of the   ations or environmental risk assessments, but provides some
                spill calculation is smaller, the impact on the spill score and the   useful concepts that can be used in such assessments.
                risk would be greater.                      The process plant incidents addressed in this evaluation include

                Secondary  containment  With  any  spill  size  scenario,  the   A blast wave or deflagration
               presence of secondary containment can be  considered as an   Fire exposure
                opportunity to reduce (or eliminate) the “area of opportunity”   Missile impact
                for consequences to  occur. Secondary containment must  be   Other releases as secondary events.
                evaluated in terms of its ability to
                                                           The secondary events become more significant as the type and
                 Contain the majority of all foreseeable spills.   storage amounts of  other hazardous materials increase. The
                 Contain 100% of a potential spill plus firewater, debris, or   F&EI is directly related to the area of exposure.
                 other volume reducers that might compete for containment   In performing F&EI calculations, the nature of the threat is
                 space-largest  tank contents plus 30 minutes of maximum   assessed by  examining three components: a material  safety
                 firewater flow is sometimes used [26].
                 Contain  spilled volumes  safely-not   exposing additional
                 equipment to hazards.                     Table 13.8  Secondary containment sample adjustment faclors
                 Contain spills until removal can be effected-no  leaks.
                                                           Condition                  Adjustmentfactor (?A)
                Note that ease of cleanup of the containment area is a secondary
                consideration (business risk).             Impervious liner                15
                 Risk is reduced as secondary containment improves. The risk   Semipervious liner   40
                                                           No immediate fill indication
                                                                                            S
                “credit” can be in the form of a reduced spill size rating or eval-   No overtlow alarms   5
                uated  as  an  independent  variable  assessing  the  dispersion   Additional equipment exposed to spilled product   IO
                potential, when secondary containment is present. In the case
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