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Hazard zone calculations 14/31 1
               Table 14.32  Representative yield factors   Flume jets
                                                            Vapor cloudfire and/orfireball-in   which a cloud encoun-
               Substance            Yield factor           ters an ignition source and causes the entire cloud to com-
                                                           bust  as  air  and  fuel  are  drawn  together  in  a  flash  fire
               Butadiene              0.03                  situation.
               Carbon monoxide        0.03                 Liquidpoolfires-not  thought to be a very high potential for
               Ethane                 0.03
               Hydrogen               0.03                  HVL releases unless ambient conditions are cold a liquid
               Methane                0.03                 pool of flammable material could form and create radiant
               Methanol               0.03                 heat hazards.
               N-Butane               0.03                  Vapor cloud explosion-
               Propane                0.03
               Styrene                0.03                  Because precise modeling is so difficult. many assumptions
               Toluene                0.03                are often employed. Use of conservative assumptions helps to
               Vinyl chloride         0.03                avoid unpleasant  surprises and to ensure acceptability of the
               Ethylene               0.06
               Propylene oxide        0.06                calculations, should they come under outside scrutiny. Some
               Acetylene              0.19                sources of conservatism that can be introduced into HVL haz-
               Methyl acetylene       0.19                ard zone calculations include
               Vinyl acetylene        0.19
                                                           Overestimation of probable pipe hole size (can use full-bore
               Source: "ARCHIE (Automated Resource for Chemical Hazard lncident   rupture as an unlikely, but worst case release)
               Evaluation)," prepared  for  the  Federal  Emergency  Management   Overestimation  of  probable  pipeline  pressure  at  release
               Agency, Department of Transportation, and Environmental Protection   (assume maximum pressures)
               Agency,  for  Handbook of Chemical Hazard Analysis  Procedures
               (approximate date 1989) and software for dispersion modeling, ther-   Stable atmospheric weather conditions at time of release
               mal, and overpressure impacts.              Ground-level release event.
                                                           Maximum cloud size occurring prior to ignition
                                                           Extremely rare unconfined vapor cloud explosion scenario
               Highly volatile liquids                     with overpressure limits set at minimal damage levels
                                                           Overpressure  effects  distance  added  to  ignition  distance
               HVL releases are complex, nonlinear processes, as discussed in   (assume  explosion  epicenter  is  at  farthest  point  from
               Chapter  7. Hazards  associated  with  the  release  of an  HVL   release).
               include several flammability scenarios, an explosion potential,
               and the more minor hazard of spilled material displacing air   These conservative parameters would  ensure that actual
               and asphyxiating creatures  in the oxygen-free space created.   damage areas are well within the hazard zones for the vast
               The flammability scenarios of concern  include the following   majority ofpipeline release scenarios. Additional parameters
               (previously described):                    that  could  be  adjusted  in  terms  of  conservatism  include
                                                          mass  of  cloud  involved  in  explosion  event,  overpressure
                                                          damage  thresholds,  effects  of  mixing  on  LFL  distance,
               Table 14.33  Expected damage for various levels of overpressure   weather  parameters  that  might  promote  more  cohesive
                                                          cloud conditions and/or cloud drift, release scenarios that do
               Peak overpressure                          not rapidly depressurize the pipeline, possibility for sympa-
               (psW       Expected damage                 thetic  failures  of  adjacent  pipelines  or  plant  facilities,
                                                          ground-level versus atmospheric events, and the potential for
               0.03       Occasional breakage of large windows under stress
               0.3        Some damage to home ceilings; 10% window   a high-velocity jet release of vapor and liquid in a downwind
                            breakage                      direction.
               0.5-1.0    Windows usually shattered; some frame damage
               1 .0       Partial demolition ofhomes; made uninhabitable   Hazard zone defaults
               2.0        Partial collapse of home wallsiroofs
               2.0-3.0    Nonreinforced concrete/cmder block walls   In the absence of  detailed hazard zone calculations, some
                            shattered                     default distances can be set based on regulatory requirements
               2.5        50% destruction of home brickwork   or  conservative  fixed  distances.  For  example,  a  type  of
               3.W.O      Frameless  steel panel buildings ruined
               5.0        Wooden utility poles snapped    hazard zone  for  a natural  gas pipeline  could  be  based  on
               5.0-7.0    Nearly complete destruction of houses   generalized distances from specific receptors such as those
               IO.        Probable total building destruction   given in Table  14.34. These are actually "distances  of con-
               14.5-29 .0   Range for 1-99%  fatalities among exposed   cern,"  rather  than  hazard  zones,  since  they  are  based  on
                            populations due to direct blast effects.   receptor vulnerability rather than damage distances from a
                                                          pipeline release.
               Source: "ARCHIE (Automated Resource for Chemical Hazard lncident   Case Study C uses a default 1250-ft radius around an 18-in.
               Evaluation),"  prepared  for  the  Federal  Emergency  Management
               Agency, Department of Transportation, and Environmental Protection   gasoline pipeline as a hazard zone, but allows for farther dis-
               Agency,  for  Handbook of Chemical Hazard Analysis  Procedures   tances where modeling  around specific  receptors has shown
               (approximate date 1989) and software for dispersion modeling, ther-   that  the  topography  supports  a  larger  potential  spill-impact
               mal, and overpressure                      radius.
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