Page 340 - Plastics Engineering
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Processing of Plastics                                         323

                  etc in the final product. Once the moulding separates from the mould, it will
                  cool more slowly and will tend to be more crystalline, have greater shrinkage
                  and lower impact strength.
                    Developments in rotational moulding are continuing, with the ever increasing
                  use of features such as
                     (i)  mould pressurisation (to consolidate the melt, remove pin-holes, reduce
                        cycle times and provide more consistent mould release),
                    (ii)  internal  heatingkooling  (to  increase  cycle times  and  reduce  warpage
                        effects).
                    In  overall terms  the disadvantages of  rotational moulding are its  relative
                  slowness and the limited choice of  plastics which are commercially available
                  in  powder form with the correct additive package. However, the advantages
                  of  rotational moulding in terms of  stress-free moulding, low mould costs, fast
                  lead times and easy control over wall thickness distribution (relative to blow
                  moulding) means that currently rotational moulding is the fastest growing sector
                  of the plastics processing industry. spical annual growth rates are between 10
                  and  12% p.a.
                  4.6.1  Slush Moulding
                  This is a method for making hollow articles using liquid plastics, particularly
                  PVC plastisols. A  shell-like mould is heated to a pre-determined temperature
                  (typically  130°C for plastisols) and the liquid is then poured  into the mould
                  to completely fill it. A period of  time is allowed to elapse until the required
                  thickness of  plastic gels. The excess liquid is then poured out and the plastic
                  skin remaining in the mould is cured in an oven. The moulding is then taken
                  from the mould.
                    It should be noted that when the plastisol liquid gels it has sufficient strength
                  to  remain  in  position  on  the  inside  surface of  the  mould.  However, it  has
                  insufficient tear  strength to be  useful and so it has to go through the higher
                  temperature curing stage to provide the necessary toughness and strength in
                  the end-product. The mould is not rotated during slush moulding.


                  4.7  Compression Moulding
                  Compression moulding is one of  the most common methods used to produce
                  articles from thermosetting plastics. The process can also be used for thermo-
                  plastics but this is less common - the most familiar example is the production
                  of  LP records. The moulding operation as used for thermosets is illustrated in
                  Fig. 4.62. A pre-weighed charge of  partially polymerised thermoset is placed
                  in the lower half of  a heated mould and the upper half  is then forced down.
                  This causes the material to be  squeezed out to take the shape of  the mould.
                  The application of  the heat and pressure accelerates the polymerisation of  the
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