Page 268 - Semiconductor For Micro- and Nanotechnology An Introduction For Engineers
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Electron-Phonon
                                  q
                             where   is the fundamental charge, N
                                                              is the conduction band effective
                                                            C
                             density of states, N   is the valence band effective density of states, n   is
                                            V                                       e
                             the electron concentration,  n   is the hole concentration,  s   and  s   are
                                                    h                       e      h
                             corrections due to enhanced electron and hole carrier scattering, and φ
                                                                                      e
                             and  φ   are corrections that take into account the phonon drag on the
                                  h
                             electrons and holes.
                Peltier      At a material junction we observe a further thermoelectric effect that is
                Heating and   reversible. Depending on the direction of current flowing through the
                Cooling
                             junction, heat is either generated or absorbed according to
                                                  ∆J =  Π  J                      (7.72)
                                                    q    AB e
                             The Peltier coefficient Π   between materials   and   defines both the
                                                                        B
                                                                   A
                                                 AB
                             sign and quantity of heat current transported per unit carrier current, and
                             is obtained from (6.41b) for isothermal conditions
                                                       η           η
                                                        n
                                                                  ∇
                                                     ∇
                                         j =  –  ( Tε σ ) ----- –  ( Tε σ ) ------ p  (7.73a)
                                         q        n  n        p  p
                                                       q           q
                                                        n            p
                                                           η
                                                          ∇
                                                i =   ( –  σ ) ----- n           (7.73b)
                                                 n      n
                                                           q  n
                                                           η
                                                          ∇
                                                i =   ( –  σ ) ------ p          (7.73c)
                                                 p      p
                                                           q  p
                             When we combine the equations in favour of the heat and carrier current
                             densities, we obtain
                                              j =  ( Tε )i +  ( Tε )i  p          (7.74)
                                                        n
                                                      n
                                                              p
                                               q
                             In an uniformly doped region, (7.74) reduces to
                                                j =  ( Tε)i =  Πi                 (7.75)
                                                 q
                             where  Π =  Tε   is the absolute thermoelectric power of the material.
                             Usually we only deal with differences between two materials adjoining at





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