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~  THE  DENSITY  AND  PHOTOELECTRIC  FACTOR  LOGS  -


        effects  will  be  automatically  accounted  for,  the  principal   THE  PHOTOELECTRIC  FACTOR  LOG
        unknown  being  the  density  of  the  organic  matter  (kero-   (or  Litho-Density)
        gen).  The  method  is  presented  below.
          The  following  assumptions  are  made  (for  details  see   9.7  Generalities
        Myers  and  Jenkyns,  1992):
                                                          The  log
        1)  The  source  rock  is  composed  of  mudrock  (matrix   The  Photoelectric  Factor  (or  PEF)  log  (the  Litho-Density
        density  =  2.70g/cm),  water  filled  porosity  (density  =   log  of  Schlumberger)  is  a  continuous  record  of  the  effec-
        1.05g/cm*)  and  kerogen  (density  =  1.1  or  1.2g/em*).   tive  photoelectric  absorption  cross  section  index  or  Pe  of
        2)  The  non-source  interval  has  the  same  mudrock  matrix   a  formation.  The  photoelectric  absorption  index  is  strong-
        density,  water  density  and  water  filled  porosity  as  the   ly  dependent  on  the  average  atomic  number,  Z,  (i.e.
        source  interval  (Figure  9.24).                 atomic  complexity)  of  the  constituents  of  the  formation,
                                                          which  implies  the  composition  and  by  inference,  the
                                                          lithology:  the  effects  of  porosity  are  kept  to  a  minimum
                           = Pos  ~ Pa
                                                          (Figure  9.25).  For  instance,  the  photoelectric  absorption
                         te   Pa  Pina             ())
                                                          index  of  a  sandstone  (quartz  matrix)  at  0%  porosity  is  Pe
                                                           1.81  while  at  35%  fresh  water  filled  porosity  it  is  Pe  1.54.
                            —   Ps—  Pras                 For  limestone  (calcium  carbonate  matrix}  the  figures  are,  at
                        Dyer   Pher  —  Dana       (2)
                                                          0%  porosity  (i.e.  matrix)  Pe  5.08  and  at  35%  porosity  Pe
                                                          4.23  (Figure  9.26)  (Gardner  and  Dumanoir,  1980).  That  is,
                                                          the  difference  between  the  Pe  values  of  the  two  matrix
              TOC%  =       0.85.  Pre  X  Peer
                                                          types  (i.e.  3.27  units)  is  more  significant  than  the  variations
                      Prer  Ce)  + Pins  (1-  $4  —  Dre)   (3)   within  each  individual  matrix  type  caused  by  porosity
                                                          changes  (i.e.  0.27  and  0.85  respectively)  (Figure  9.26).
        Where:
                                                          Principal  uses
        p,,  =  density  non-source  interval  (average  from  log)
                                                          The  photoelectric  absorption  index  is  used  principally  in  a
        p,  =  density  source  interval  (from  log)
                                                          quantitative  manner  as  a  matrix  indicator,  either  alone  or,
        Pras  =  2-70g/em?,  assumed  mudrock  density
                                                          especially  when  cross-multiplied  with  the  corresponding
        ,  =  water  filled  porosity,  derived  with  equation  (1)
                                                          density  log  vatue,  to  produce  the  value  U  (Table  9.10).
        ,_,  =  kerogen  filled  porosity,  derived  with  equation  (2)
                                                          Qualitatively,  in  the  correct  borehole  environment,  it  can  be
        P,.,  =  1.1  or  1.2g/cm’,  kerogen  density
                                                          used  to  indicate  lithology  and  certain,  mainly  diagenetic
        P,  =  1.0Sg/cm’,  density  water
                                                          minerals.
        TOC%  =  0.85  X  wt.%  kerogen
                                                            The  use  of  the  litho-density  log  is  severely  restricted  by
                                                          the  fact  that  it  is  ineffective  in  holes  with  barite  weighted
        The  water  filled  porosity  of  the  contiguous  non-source
                                                          mud,  since  the  photoelectric  absorption  index  for  barite  is
        interval  is  given  by  equation  (1).  The  volume  (porosity)
                                                          nearly  150  times  that  of  most  of  the  common  minerals’
        filled  with  kerogen  of  a  given  density  is  given  by  equation
                                                          and  when  present  will  dominate  the  log  response.  If  the
        (2).  The  conversion  of kerogen  volume  to  weight  and  then
                                                          log  is  to  be  used  effectively,  the  drilling  mud  must  not
        TOC%  using  a  weight  %  kerogen  equivalence  to  weight
                                                          contain  barite.
        %  carbon  of  0.85,  is  given  by  equation  (3).
                                                            The  litho-density  log  is  sometimes,  misleadingly,
                                                          called  the  lithology  tog.  It  is  not:  it  is  a  log  of  the
                                                          effective  photoelectric  absorption  index.  Its  response  is
                        an

                        Re          KEROGEN   ~RSe  aN    no  closer  to  the  lithology  than  that  of  any  other  log.
                        NEN         ee  or'1:2  gfemi   §  \

                        NSN                    NBN         Table  9.10  Principal  uses  of  the  photoelectric  factor
              MATRIX    REN                    N2Q
                          =                    N=          (PEF)  log.
            p,,  =  2.7g/em?  Rs  \   matrix   Kn \
                                                                     Dicipline
                                                                                 Used  for
                                                                                               Knowing
                        NaN        Pa,  =  2.7giem? |  &N
                        NN
                                               NN
                        NEN                    NEA         Quantitative   Petrophysics   Matrix   Pinan, 2
                        REN
                                               NEA
                                                                                  identification
           NON-SOURCE             SOURCE  ROCK
                                    (immature)                                   Ursa          Vans, U,

        Figure  9.24  Schematic  basis  for  using  the  density  log   Qualitative   Geology   Matrix  type   mineral
        quantitatively  to  derive  total  organic  carbon,  TOC.  The  matrix                  values
        and  water  content  characteristics  are  assumed  identical  in        Diagenetic    elemental
        both  the  source  and  non-source.  Kerogen  is  an  additional  part    minerals      values
        of  the  total  volume  in  a  source  rock.

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