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74    Cha pte r  T h ree


                  (4)  ASTM F 487-06, Standard Specification for Fine Aluminum-
                    1% Silicon Wire for Semiconductor Lead Bonding. (Most of
                    the same information as in F 72 above but for Al, 1% Si wire.)
                 (5)  ASTM F 584-06, Standard Practice for Visual Inspection of
                    Semiconductor Lead-Bonding Wire. (This may be discontinued
                    but is useful as it gives manual procedures and photographs
                    of acceptable and unacceptably cleaned bonding wires.)


         Appendix 3B
              Copper Wire Bonding, a Low-Cost Solution to Gold Wire Bonding?
                 From Industry Newsletter & Technical Publication, Volume III,
              Issue 4, July 2005. (Used with Permission of COORS TEK/GAISER
              precision bonding tools.)
                 Introduction: Part one of this discussion covered aspects of the
              ball formation; the various ways to achieve size and shape consis-
              tency. In this section, the material properties in particular the hard-
              ness and the impact on ball bonding will be discussed. The copper
              bonding process is not simply about how to make a good free-air
              ball but how to achieve good product quality and reliability.
                 The Facts:
                 Copper is a good electrical and thermal conductor, better than
                 gold (see Table 3B-1).
                 Copper wire is harder than gold (see Table 3B -1).
                 Copper as a raw material is cheaper and more abundant than gold
                 (>$0.20/oz. vs. >$800/oz).
                 Copper oxidizes easily, gold does not.
                 Copper wire bonding uses a limited number of specially designed
                 capillaries, gold wire does not.
                 Copper processing requires special hardware to prevent oxidation,
                 gold does not.
                 Copper when bonded to Aluminum pads forms thin inter-
                 metallic layers, Gold forms thick intermetallic layers (see gold
                 in Fig. 3B-1).


                      Typical Parameter       Cu        Au
                                  −6
                      Resistivity (×10  ohm/cm)  1.6    2.3
                      Wire Hardness (HK)      >64       <60
                      Ball Hardness (HK)      >50       <39
                      Looping                 Excellent  Excellent

                    (HK) = Knoop Hardness
                    TABLE 3B-1  Characteristics of Cu and Au Wires
   90   91   92   93   94   95   96   97   98   99   100