Page 207 - Basic physical chemistry for the atmospheric sciences

Index 1 9 3

cinnabar (HgS), thermodynamic proper- crystallization (precipitation), from solu­
ties of, 1 7 0 tions, 68
citric acid, in lemon juice, 83 crystals, entropy of, 26
2
cleaning agents, Freon use as, 149 cupric ion [copper (II); Cu + ] , thermody­
cloud drops, sulfur dioxide conversion to namic properties of, 1 6 9
sulfuric acid in, 1 3 2 cupric oxide (CuO), use in catalytic con­
cloud physics, homogeneous and hetero­ verters, 58
geneous processes in, 67 cuprite (Cu20), thermodynamic proper­
s
cloud . See also polar stratospheric ties of, 169
clouds (PSCs) cuprous chloride (CuCI), dissolution and
nitrogen pentoxide formation in, mecha­ equilibrium of, 74-75
)
nism, 48-49 cuprous ion [copper (I ; Cu + ] , thermody­
pH of water in, IOI namic properties of, 1 6 9
sulfuric acid dissolution in water of, cylinder-piston example, of first law of
-
100 I O I , 103 thermodynamics, 1 8 - 1 9
coal burning, atmospheric sulfur dioxide
from, 132 D
cobalt sulfide (CoS), solubility (or ion) deca (prefix), definition and symbol for,
product constant for, 1 6 6 1 5 7
7
colligative properties, of solutions. 1 - 72 decimal multiples of units, prefixes for,
solute effect , 77 1 5 7
s
collision theory of gaseous reactions, 52- deci (prefix), definition and symbol for,
57, 66 157
complex ions degree Celsiu , definition and symbol for,
s
formation constants of, 97, 168 1 5 7
properties of, 96-97 denitrification, in polar stratispheric
s
s
concentrations. of solution , 69-70 cloud , 1 5 1
configurations, of molecules, potential en­ detailed balancing, principle of, 5 1 , 66
ergy based on, 17 diamond (C), thermodynamic properties
conjugate acid-base pairs, 86-87, IOI of, 1 6 9
of weak acids and bases, as buffers, dichromate ion (Cr2 � - ) . 1 72
94 dihydrogen phosphate ion (H2PO-.J, 1 7 2
conservation, principle of, 17 equilibrium (or dissociation) constant
constants, list of, 1 5 8 for, 1 6 3
conversion factors, list of, 1 5 8 dirty-water analogy, of chemical resi­
e
copper (Cu) dence tim , 59-60
atomic weight of, 159 dissociation constant. See equilibrium (or
electrode potential of, 1 2 0 acid- dissociation or ionization) con­
oxidation in air, 1 3 5- 1 3 6 stant(s) and under various chemical
thermodynamic properties of, 1 6 9 species
use in electrodes , 1 1 5 , 1 1 6, 1 3 6 dissociation energy, of chemical bonds,
copper carbonate (CuC03), solubility (or 140
ion) product constant for, 166 DNA damage, ozone column relation to,
copper-copper half-cell, 104, 1 1 8 1 5 6
copper-hydrogen electrochemical cell, droplet, formation by condensation, 35-
standard half-cell potential of, 1 1 8- 37
1 1 9
copper (II) ion (cupric ion ), 1 7 2 E
copper (I) ion (cuprous ion), 1 7 2 Eh
copper sulfide (CuS) natural limits to, 1 3 0
pH compared to, 1 2 8
solubility (or ion) product constant for ,
166 as symbol for redox potential, 1 2 8
thermodynamic properties of, 1 6 9 Eh-pH diagram, example of, 1 3 1
coulomb. definition and symbol for, 1 5 7 einstein
covalent compounds, oxidation numbers energy of, 1 5 5 , 185
for, 106 as unit of photons, 1 3 9
covellite. See copper sulfide electric capacitance, SI unit of, 1 5 7