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                       372                                 Fracture Mechanics: Fundamentals and Applications





















                                                               FIGURE 8.14 Effect of notch radius on the Izod
                                                               impact strength of several engineering plastics. Taken
                                                               from D 256-03, “Standard Test Methods for Deter-
                                                               mining the Izod Pendulum Impact Resistance of
                                                               Plastics.” American Society for Testing and Materials,
                                                               Philadelphia, PA, 1988.

                       energy required to fracture the specimen is inferred from the initial and final heights of the pendulum
                       (Figure 7.37). In the case of the Izod test, the specimen is a simple cantilever beam that is restrained
                       at one end and struck by the pendulum at the other. One difference between the metals and plastics
                       test methods is that the absorbed energy is normalized by the net ligament area in plastics tests,
                       while tests according to ASTM E 23 report only the total energy. The normalized fracture energy
                       in plastics is known as the impact strength.
                          The impact test for plastics is pervasive throughout the plastics industry because it is a simple
                       and inexpensive measurement. Its most common application is as a material-screening criterion.
                       The value of impact strength measurements is questionable, however.
                          One problem with this test method is that the specimens contain blunt notches. Figure 8.14
                       [17] shows the Izod impact strength values for several polymers as a function of notch radius. As
                       one might expect, the fracture energy decreases as the notch becomes sharper. The slope of the
                       lines in Figure 8.14 is a measure of the notch sensitivity of the material. Some materials are highly
                       notch sensitive, while others are relatively insensitive to the radius of the notch. Note that the
                       relative ordering of the materials’ impact strengths in Figure 8.14 changes with notch acuity. Thus
                       a fracture energy for a particular notch radius may not be an appropriate criterion for ranking
                       material toughness. Moreover, the notch strength is often not a reliable indicator of how the material
                       will behave when it contains a sharp crack.
                          Since Izod and Charpy tests are performed under impact loading, the resulting fracture energy
                       values are governed by the short-time material response. Many polymer structures, however, are
                       loaded quasistatically and must be resistant to slow, stable crack growth. The ability of a material
                       to resist crack growth at long times is not necessarily related to the fracture energy of a blunt-
                       notched specimen in impact loading.
                          The British Standards Institution (BSI) specification for unplasticized polyvinyl chloride (PVC-U)
                       pipe, BS 3505 [18], contains a procedure for fracture toughness testing. Although the toughness
                       test in BS 3506 is primarily a qualitative screening criterion, it is much more relevant to structural
                       performance than the Izod impact test.
                          Appendices C and D of BS 3506 outline a procedure for inferring the toughness of a PVC-U
                       pipe after exposure to an aggressive environment. A C-shaped section is removed from the pipe of
                       interest and is submerged in dichloromethane liquid. After 15 min of exposure, the specimen is
                       removed from the liquid and the surface is inspected for bleaching or whitening. A sharp notch is
                       placed on the inner surface of the specimen, which is then dead-loaded for 15 min or until cracking
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