Page 121 - Fundamentals of Gas Shale Reservoirs
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1                                                    1
                                                 PCM                                                CCM
                                                8 10  9            0.8                              17    18
               0.8
             Pore size distribution (%)  0.6    12    13          Pore size distribution (%)  0.6   23    24
                                                      11
                                                                                                    20
                                                                                                          21
                                                                                                    25
                                                14
                                                      15
                                                                                                          26
                                                                   0.4
                                                                                                    27
               0.4
                                                                   0.2
               0.2
                                                                     0
                0                                                    0.01   0.1    1     10     100  1,000  10,000
                0.01   0.1     1     10    100   1,000  10,000                       relaxation time (ms)
                              T 2  relaxation time (ms)                           T 2
                                                                 FIGurE 5.21  NMR T  relaxation time distribution of fully satu­
            FIGurE 5.20  NMR T  relaxation time distribution of fully satu­       2
                              2
            rated PCM samples.                                   rated CCM samples.

            TabLE 5.4  Nmr CPmG T  relaxation time results from the PCm and CCm samples collection
                                  2
                         Partially saturated                             Brine saturated
                               Total                  Porosity contribution        Porosity Contribution   Total
            Samples   T  (ms)  porosity (%)  T  (ms)  @ T  (%)           T  (ms)   @ T  (%)           porosity (%)
                       2s                     2s          2s              2L          2L
              8        0.29        3.2        0.46           97           30.1            3              11.4
              9        0.38        5.2        0.43           89           27.3            11             10.8
            10         0.4         2.2        0.43           82           22.6            18              6.7
            12         0.32        1.9        0.5            80           12              20             14.2
            13         0.36        2.3        0.56           68           29.2            32             11.55
            14         0.32        2.7        0.51           93           20.6            7              14
            15         0.32        2.5        0.56           79           30.2            21             18.5
            17         0.35        5.8        0.89           92           26.1            8              15.75
            18         0.35        5.2        0.4            96           12              4              10.80
            20         0.35        5.2        0.5            100            —             —              12.76
            21         0.36        4.8        0.45           96            8.4            4              14.20
            23         0.36        6.5        0.45           100            —             —              11.30
            24         0.36        3.6        2.73           96           64.3            4              14.00
            25         0.4         3.5        0.63           100            —             —              18.50
            26         0.36        2.8        3.06           85           64.3            15              9.63
            27         0.36        5.3        0.89           93           26.1            7              11.40
            Two T  populations are recorded: a short T  and a long T .
                2
                                       2s
                                                2L
                    (a)                                        (b)



                                           I
                                                                                 Q



                       Q                                                            K
                                   I
                                                                       K
                                                                                   Q        I
                                                         Q

                    1  m      EHT = 5.00 kV  Signal A = SE2  Aperture size = 30.00  m           30  m
                              WD = 10.0 mm                       B  Px:97 nm
            FIGurE 5.22  (a) SE image of sample 14 displaying dominant illite and quartz particles (b) BSE image of sample 20 displaying dominant
            kaolinite, Illite, and quartz particles.
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