Page 217 - Fundamentals of Gas Shale Reservoirs
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MATURITY EFFECTS   197
                            (a)

                               9000  Water saturation                                        1
                               8500
                               8000
                               7500
                              V s  (ft/s)  7000
                               6500
                               6000
                               5500
                               5000                                                          0
                                 8,000  9,000  10,000 11,000 12,000 13,000 14,000 15,000
                                                        V  (ft/s)
                                                         p
                            (b)
                               9000                                                         20
                               8500                                                         18
                               8000                                                         16
                               7500                                                         14
                               7000                                                         12
                              V s  (ft/s)  6500                                             10  TOC (%)

                                                                                            8
                               6000
                               5500                                                         6
                               5000                                                         4
                               4500                                                         2
                               4000                                                         0
                                   0.8   0.9    1     1.1   1.2    1.3   1.4    1.5   1.6
                                                          V  (ft/s)                  ×10 4
                                                            p
            FIGURE 9.3  V –V  plots of partially saturated shales: (a) Sonic log data from a Bossier/Haynesville well (from Lucier et al., 2011) and (b)
                           s
                        p
            laboratory measurements on dry (open squares), partially (open triangles and solid circles color coded with respect to TOC content), and fully
            saturated (solid triangles) shales shown in Table 9.1. The Castagna mudrock line (black) is shown in for reference in both plots.

            and  had clay content of ~30% (illite)  with the rest com­  The laboratory measurements on shales whose water sat­
            prising dolomite, K‐feldspar, and quartz. Porosity was ~5%.   uration ranges from 0 to 1 demonstrate significant effect of
            Essentially,  these were  hard, laminated  Proterozoic  shales   saturation on V  that follow the same trend as the one obtained
                                                                            p
            comprising mainly rigid grains and have similarities in com­  for sonic velocities of mature shales. Given that both sonic
            position to other gas shales (e.g., Tutuncu, 2012) except for   log and ultrasonic velocity show significant effects of partial
            the lack of organic matter. Modal pore sizes were in the   saturation, theoretical models might need to be modified.
            region of 10 nm. These shales were tested in the fully pre­
            served state (i.e., S  = 100%) and a partially saturated state
                           w
            (S  ~ 40%). The authors noted that P‐wave velocity decreased   9.5  MATURITY EFFECTS
             w
            with decreasing water saturation (i.e., increasing gas (air)
            saturation)  but  S‐wave  velocity  increased  by  about  20%.   The  thermal  maturity  determines  the  producible  hydro­
            These changes led to increases in Young’s and shear moduli   carbon type and, along with mineralogy of nonorganic con­
            and a decrease in bulk modulus with increasing gas satura­  stituents, is believed to control their brittleness. ORS thermal
            tion. Large shear moduli changes have also been noted   maturity estimation from surface seismic data is practically
            by Ghorbani et al. (2009) in more clay‐rich shales and may   important for more robust reservoir characterization  and
            be due to large effective stress increases associated with   reliable “sweet spot” detection. Evaluation of the ORS matu­
            capillary suction in rocks with such small pore sizes   rity from indirect seismic measurements might be achieved
            (L. Laloui and A Ferrari, Personal Communication, 2013).   by using correlations between elastic properties, kerogen
            It  is   currently  unknown whether methane–organic matter   content, microstructure, and maturity obtained from con­
            interactions would result in different rock physics responses   trolled laboratory measurements. Several studies have been
            as compared to the water–air capillary system in these tests.  undertaken to identify key parameters that can be used to
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