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338                            Fundamentals of Water Treatment Unit Processes: Physical, Chemical, and Biological










                                                                                                  140
                          140
                                                                                                  120
                          120
                                                                                                  100
                         C (mg sus. solids/L)  80                                                 60
                          100
                                                                                                  80
                           60
                                                                                                  40
                           40
                                                                                                  20
                           20
                            0                                                                     0



                                  0                                                          1440
                                   2                                                     880
                                     4  6
                                        8                                            440
                                         10  12  Z (cm) 18  20  22  24  26  28  30  32  180  240  320 Time (min)
                                            14
                                              16
                                                           34
                                                             36
                                                              40
                                                                44
                                                                      80
                                                                 48
                                                                  20
            FIGURE 12.8  C(Z, t) plot of computed output of Ives’ model. (Adapted from Ives, K.J., Trans. ASCE, 127(Part III), 372, 1962.)
                    C
                                                Floc saturation zone
                                                      C '    ΔC(breakthrough)  =  v  ΔC(wave-front)
                                                   t                         wf   •
                                                              Δt(breakthrough)  ΔZ(wave-front length)
                                                                                      ΔZ(wave-front advance)
                                                                               t'  v wf   =
                                 Wave front                                           Δt(wave-front advance)
                                 at start of
                                 steady state
                                   shape             ΔC(wave-front)  v(wave-front)
                           v(wave-front)
                                                                                             ΔC(breakthrough)



                    Exponential decline                   ΔZ(wave-front                        ΔZ(wave-front
                                                                                                advance)
                                                           length)
                                                                                     Δt(wave-front
                                                                                              advance)
                                                                                         Δt(breakthrough)

                                                                Z                         Z'

            FIGURE 12.9  Emergence of the wave front at bottom of filter column and formation of breakthrough curve showing the associated
            mathematical relationships.


            as time increases. Also, as seen in Figure 12.9 (and in  bottom of the filter column, it defines the ‘‘breakthrough’’
            Figures 12.8 through 12.10) the wave front is steady state  curve, which is seen as the C(t) Z curve perpendicular to
            in shape and it translates along the depth of the column. The  the Z-axis.
            wave front translation is due to increasing solids accumula-  In depicting Equation 12.5 consider the wave front for
            tion within the medium. As the wave front emerges from the  the increment of concentration, DC(wave front) with
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