Page 392 - Instrumentation Reference Book 3E
P. 392

Potentiometry and specific ion measurement  375






                                                            -1  1
                                                                        Figure 17.32  Diagrammatic
                                                            -12         arrangement of componentsfor
                                                                        an ion-selective monitor.
                                                                  13    Courtesy ABB Instrument
                                                                        Group. 1. solenoid valve
                                                                  14    (energizes during
                                                                        standardization to connect
                                                                        primary standard solution);
                                                                        2. solenoid valve (energizes to
                                                                        admit emergency sample supply
                                                                        when sample is lost in the
                                                                        header tank); 3. flow cell:
                                                                        4. earthing tube; 5. sodium
                                                                        electrode; 6. SUPPLY ON lamp
                                                                        (illuminates when power is
                                                                        connected to the monitor):
                                                                        7. 8020 100 amplifier; 8.8033
                                                                        200 current output moduie;
                                                                        9. SERVICE lamp (red) and ON-
                                                                        LINE lamp (green) with push-
                                                                        button (optional feature);
                                                                        10. digital display module (linear
                                                                        motor readout optional):
                                                                        11.8060 300 compensation
                                                                        module;l2. 8021 400 alarm and
                                                                        temperature control module;
                                                                        13.8020 500 power supply;
                                                                        14.8020 600 function module;
                                                                        15. electrodes connection point
                                                                        (junction box); 16. refillable
                                                                        calomel reference electrode;
                                                                        17. peristaltic pump; 18. gas
                                                                        debubbler; 19. manual
                                                                        SAMPLE/CALIBRATE valve;
                                                                        20. flow cell drain; 21. secondary
                                                                        standard solution container
                                                                        (1 liter) (heat exchanger located
                                                                        behind the panel at this point):
                                                                        22. buffer solution container
                                                                        (500 ml)





             Table 17.9  Avaiiable ion-selective electrodes
             Solid-state membrane   Glass membrane      Liquid ion exchange    Gus-sensing
             electrodes             electrodes          membrane electrodes    electrodes

             Fluoride               PH                  Calcium                Ammonia
             Chloride               Sodium              Calcium + magnesium    Carbon dioxide
             Bromide                Potassium           (is.: water hardness)   Sulphur dioxide
             Iodide                                                            Nitrous oxide
             Thiocyanate                                                       Hydrogen sulphide
             Sulphide                                                          Hydrogen fluoride
             Silver                                     Barium
             Copper                                     Nitrate
             Lead                                       Potassium
             Cadmium
             Cyanide
             Redox
             pH (antimony)
   387   388   389   390   391   392   393   394   395   396   397