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Lithographic Patterns 113



                                                       reacts with the resist during baking, and forms a non-
                                                       soluble layer on the sidewalls of the contact hole,
                                                       making the hole smaller (should there be photoresist
                                                       residue at the bottom, it would block the contact hole).
                                                       0.25 µm contact holes have been reduced to 0.10 µm
                                                       with this method.


                                                       10.5 LITHOGRAPHY SIMULATION
           Figure 10.8 Resist trimming: resist lines made narrower
           by isotropic etching of the resist in oxygen plasma.  The lithographic pattern formation starts with the
           Resolution (line + space) remains constant
                                                       designer’s layout file, which is turned into a physical
                                                       mask plate in a mask shop. This mask is inserted into the
           photoresist is then performed (Figure 10.8). Resist line  exposure tool, where it modifies the illumination from
           gets narrower and thinner. This method is most suitable  the light source. After complex photochemistry steps
           when reasonably narrow lines can be used as starting  in the photoresist, development creates patterns in the
           point. Lines of 1.0 µm original width and thickness can  resist (Figure 10.10). This information flow has many
           be narrowed down to 0.2 µm; a 0.4 µm horizontal nar-  points where errors can occur, and where dimensions
           rowing from both sides. Resist thickness after thinning is  are not accurately transferred. Some of these are data
           0.6 µm because isotropic thinning was employed. This  errors related to formats used in drawing and mask
           is a useful approach for studying simple structures, such  writing, and some are physical, and related to both
           as individual lines of scaled-down dimensions. Small  mask writing and exposure resolution, and to etching
           MOSFETs of ca. 20 nm gate lengths have been made by  tolerances.
           resist trimming by using a 200 nm initial linewidth. But  It should be noted that the mask writing process has
           line plus space remains intact, and no more devices can  a similar information flow and similar error sources: the
           be made to fit on a wafer.                   mask writer has finite resolution, the photoresist used
                                                       in mask writing is similar to resists used in optical
                                                       lithography, and chrome etching has its non-idealities
           10.4.3 Chemical shrink of dark field structures  just like any other etching process.
                                                         Lithography simulation is a self-contained speciality
           The resist thinning method does not work for dark  within simulation. It is partly physical simulation
           field patterns: any loss of linewidth will result in  (optical modelling) and partly semiempirical simulation
           wider structures. A poor man’s method of small DF  like etch simulation (development modelling).
           structures is based on resist flow: resist will flow  Lithography simulators have three basic functions
           when heated above glass-transition temperature. This  as shown in Figure 10.11. The first module is optical
           flow will, under favourable conditions, make holes and  modelling, the second is photochemical, time-dependent,
           trenches smaller in a controlled fashion. This method has  diffusion modelling and the third module is an etch sim-
           been successfully used in contact hole scaling studies.  ulator specifically developed for resists (Figure 10.11).
             A more advanced version for making narrow dark  Development of a novolak resist in an alkaline devel-
           field patterns consists of patterning, overcoating, baking  oper is an etching reaction, and it uses models similar to
           and rinsing (Figure 10.9). The overcoating material  etching, but because its application field is very specific,










                             (a)            (b)             (c)             (d)
           Figure 10.9 Chemical shrink technology for contact hole narrowing: (a) minimum contact hole exposed by optical
           lithography; (b) polymer deposition; (c) curing and (d) washing away the unreacted polymer. Redrawn from Ishibashi, T.
           et al. (2000), by permission of Institute of Pure and Applied Physics
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