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2.3 Fabrication Techniques                                                     21

                  to the silicon at the bottom of a cavity is required. In these cases difficulties arise,
                  first, with step coverage and, second, with the minimum feature sizes that can be
                  obtained. Resist coverage over a deep step is very nonuniform, with the resist thin-
                  ning as it passes over the top edges and thickening at the bottom edges of a cavity
                  leading to a disparity in the exposure and development conditions required for opti-
                  mization. Typical resist profiles are illustrated in Figure 2.9. The thinner resist on
                  the top edges requires short exposure and development times so that feature line
                  widths are not reduced and the thicker resist at the bottom edges of the cavity
                  requires long exposure and development times so as not to leave unwanted fillets of
                  resist running around the bottom edges of the cavity. By using thicker resists and
                  slower spin speeds the problem is reduced, although it can never be entirely elimi-
                  nated, except by spray deposition. The bottom of the cavity will also be out of con-
                  tact with the mask in a contact aligner and out of focus in a wafer stepper. However,
                  most contact aligners have a sufficiently collimated beam for minimum line widths
                  of 10 µm to be achieved at the bottom of a 400-µm deep cavity. Similar results can
                  be obtained with a stepper.


                  2.3.3  Etching
                  Much of the early work on MEMS utilized micromachining using wet chemical
                  etching; and although IC processing is dominated by dry etching, the majority of
                  etch processing done in MEMS fabrication is still done using wet chemical etchants.
                  In both wet and dry etching, consideration is given to the isotropy of the etch and
                  the etch selectivity to the masking material and other exposed materials. The etch
                  selectivity is defined as one film etching faster than another film under the same
                  etching conditions.
                      Wet etchants used for etching silicon dioxide, silicon nitride, and aluminum are
                  well known in the semiconductor industry. These are all isotropic etchants, which
                  means they etch at the same rate in all directions. Wet etchants for silicon, on the
                  other hand, may be either isotropic or anisotropic. The anisotropic silicon etchants
                  etch crystalline silicon preferentially in certain directions in the crystal. For all the
                  wet chemical etchants used in MEMS, the etchant and masking material can usually
                  be chosen to give a highly selective etch.
                      Dry etching is done in a weakly ionized plasma at low pressure. Most dry etch-
                  ing is a combination of chemical and physical etching. Chemical etch processes give
                  good selectivity and isotropic profiles are obtained, but physical etch processes have
                  low selectivity and induce damage from ion bombardment. However, physical etch



                                   Resist profile over
                                   wide trench




                                   Resist profile over
                                   narrow trench

                  Figure 2.9  Profiles of resist over wide and narrow trenches. Note the thinning of the resist near
                  to the top edges and the thicker resist at the bottom edges of the wide trench.
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