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                                               LIGA and


                                               Micromolding






                                               4.1   Introduction  ......................................................................4-1
                                               4.2   LIGA — Background ........................................................4-3
                                                     History • Synchrotron Orbital Radiation (SOR)
                                                     • Access to the Technology
                                               4.3   LIGA and LIGA-Like Process Steps ..................................4-9
                                                     X-Ray Masks • Choice of Primary Substrate
                                                     • Resist Requirements • Methods of Resist Application
                                                     • Exposure • Development • Comparison of Master
             Guangyao Jia and                        Micromold Fabrication Methods • Metal Deposition
             Marc J. Madou                           • Molding • Demolding • Alternative Materials in LIGA
             University of California, Irvine  4.4   Examples  ..........................................................................4-69






             4.1 Introduction


             LIGA is the German acronym for X-ray lithography (X-ray lithographie), electrodeposition (galvanofor-
             mung), and molding (abformtechnik). The process involves a thick layer of X-ray resist (from microns to
             centimeters), high-energy X-ray radiation exposure, and development to arrive at a three-dimensional
             resist structure. Subsequent metal deposition fills the resist mold with a metal, and after resist removal,
             a freestanding metal structure results [IMM, 1995]. The metal shape may be a final product or serve as
             a  mold  insert  for  precision  plastic  molding. Molded  plastic  parts  may  in  turn  be  final  products  or
             lost molds (see Figure 4.1). The plastic mold retains the same shape, size, and form as the original resist
             structure but is produced quickly and inexpensively as part of an infinite loop. The plastic lost mold
             may generate metal parts in a second electroforming process or generate ceramic parts in a slip casting
             process.
               The  bandwidth  of possible  sizes  in  all  three  dimensions  renders  LIGA  useful  for  manufacture  of
             microstructures  (micron  and  submicron  dimensions)  and  packages  for  these  microstructures  (milli-
             meter  and  centimeter  dimensions), and even  for  the  connectors  from  those  packages  to  the “macro
             world” (electrical, e.g., through-vias; or physical, e.g., gas in- and outlets).
               Once LIGA was established in the research community, interest in other micro- and nano-replication
             methods became more pronounced. Given the cost of the LIGA equipment, various LIGA-like processes
             took center stage. These pseudo-LIGA methods involve the replication of masters created by alternate
             means  such  as  deep  reactive  ion  etching  (DRIE)  and  novel  ultraviolet  thick  photoresists. This  more
             generalized lithography and replication procedure is illustrated in Figure 4.2.



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