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Strain and Pressure Sensors Based on OFET   105


                           2.4 × 10 –3
                           2.0 × 10 –3
                           1.6 × 10 –3
                           1.2 × 10 –3
                           8.0 × 10 –4
                           4.0 × 10 –4
                                    0   2   4   6   8  10  12
                                           Pressure (kPa)
                                               (a)

                             –23
                             –24
                            Average V t  (V)  –26
                             –25

                             –27
                             –28
                             –29
                                  0   2    4   6   8   10  12
                                          Pressure (kPa)
                                              (b)

               FIGURE 3.13  (a) Average mobility vs. pressure (three samples); (b) average
               threshold voltage vs. pressure (three samples). (Reprinted from Ref. 16.
               Copyright 2007, with permission from Elsevier.)


               the reduced performance of bottom-contact devices when compared
               to top-contact devices. An example of the obtained results is shown
               in Figs. 3.14 and 3.15.
                   The threshold voltage decreases with pressure in bottom-contact
               devices while in top-contact devices it is pressure-insensitive. This
               observation confirms the role of insulator/semiconductor and metal/
               semiconductor interfaces in determining the pressure sensitivity of
               the device. On the other hand, mobility has a very similar behavior in
               top-contact and in bottom-contact devices, indicating a direct contri-
               bution of the semiconductor mobility in the channel to the observed
               sensitivity. Even if a complete explanation of the observed sensitivity
               needs additional investigation, it seems likely that the effect is quite
               reasonable since the transport properties of organic molecular sys-
                                                                  14
               tems follow the hopping model rather than the band model.  Under
               compressive strain, the energy barrier for hole hopping decreases
               due to the smaller spacing between molecules, resulting in an increase
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