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Scaling Effects in Organic Transistors and Transistor-Based Chemical Sensors   7



                                                      SiO 2
                                                            +
                                                           n  Si














                                         Side                     Drain
                         Source          guard          Gate
                       SMU1            SMU2          SMU3
                              Semiconductor Parameter Analyzer  SMU4

               FIGURE 1.4  Three-dimensional device structure and circuit diagram for the
               function of side guards in a nanoscale transistor used as chemical sensor.
               To collect spreading currents traveling through the area outside the defi ned
               channel, two side guards were designed on the two sides of the channel,
               unconnected to and kept at the same potential as the drain. The three layers
               from top are bottom-contact pentacene and Au/Ti electrodes (surface shown
                                                        +
               by a SEM image of real device), SiO  as dielectric, and n  Si as gate. Each SMU
                                         2
               (source measurement unit) of the Semiconductor Parameter Analyzer (Agilent
               4155C) supplies voltage and measures current independently. SMU1, 2, 3,
               4 serves as the source, side-guard, gate, and drain, respectively. SMU1 =
               ground; SMU3 = V ; SMU2 and SMU4 were set at the same value V .
                             g                                    ds
               (Reprinted with kind permission from Springer Scientifi c + Business Media. )
                                                                      68
               side guards (I  ) and also with the side guards biased (I ). For
                            open                                   ds
               nanoscale devices,  I  and  I   manifested different behaviors.  I
                                 ds    open                            open
               behaved more as a long-channel FET, which indicates a substantial
               component of spreading current. For each of the measured devices,
               the maximum value of I  was significantly lower than that of I
                                    ds                                 open
               under the same voltage configuration, and the ratio  I /I   was
                                                               ds  open
               below 70%. This ratio was found to positively correlate to the W/L
               ratio. The distance from a channel to its side guards and the geometry
               of the electrodes may actually affect its I /I   ratio.
                                                 ds  open
               1.1.3  Channel Length and Temperature Dependence
                       of Charge Transport in Organic Transistors
               Although there have been reports of electrical characteristics at room
               temperature for OTFTs with submicron and nanoscale channel
               lengths, 37–40  no experimental study has been conducted systematically
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