Page 453 - Organic Electronics in Sensors and Biotechnology
P. 453

Purified DNA         DNA-CTMA





                     –
                  CH Cl
                    3
                   +
               H C  N  (CH ) 2 15 CH 3  +                          + NaCl
                3
                   CH
                    3
            HexadecylTriMethyl
            Ammonium Chloride



          FIGURE 8.5  The purifi ed DNA is initially soluble only in aqueous solutions and does
          not dissolve in any organic solvent. Purifi ed DNA is modifi ed through a cationic
          surfactant (hexadecyltrimethyl ammonium chloride––CTMA) cation exchange reaction
          to enhance solubility, processing, and stability.


                 Before programming;             After programming; charge
                   no charge stored                 stored in FG/electret

                       G
                       FG                              +++++++

             S                    D
                      Closed
                                                         Open
            Semiconductor substrate
                                        (a)


             S                    D
                      Closed
                                                         Open
            Semiconductor layer
                      Electret                        ++++++++++
                        G
                                        (b)

          FIGURE 8.7  Methods against memory loss. The basic transistor is a device in which
          a small voltage applied at the control gate (G) modulates a much larger current fl ow
          from source (S) to drain (D) through a semiconductor substrate. (a) In fl ash
          memories, an amount of charge is trapped on a fl oating gate (FG) that modifi es the
          control voltage required for current to fl ow from S to D. Whether current fl ows or not
          defi nes a boolean 1 or 0. The memory of this state persists as long as the charge
          remains trapped on the fl oating gate. (b) In Baeg and colleagues’ organic device
          shown, the same principle is used, but the charge is trapped locally on a thin
          electret of chargeable polymer, rather than on an isolated fl oating gate. 73
          (Reproduced with permission from Ref. 77. Copyright 2004, Nature Publishing Group.)
   448   449   450   451   452   453   454   455   456   457   458