Page 185 - Pipeline Rules of Thumb Handbook
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172     Pipeline Rules of Thumb Handbook

                 K = Valve coefficient of discharge                                    Table 1
                P 1 = Inlet pressure, psia (set pressure + accumulation   Gas Constant Based on Ratio of Heats
                    + atmos. pres.)
                                                                     Gas             Mol. Wt.      C p /C v    C

                                                               Acetylene              26            1.26       343
                            Subsonic flow
                                                               Air                    29            1.40       356
                                                               Ammonia                17            1.31       348
           The second general category for vapor or gas sizing is gen-
                                                               Argon                  40            1.67       378
         erally when P 2 is greater than half of P 1 (backpressure greater  Benzene   78            1.12       329
         than half of inlet pressure).                         Butadiene              54            1.12       324
           Using  k (ratio of specific heats) and  P 1 /P 2 (absolute),  Carbon dioxide  44          1.28       345
         confirm from Fig. 1 that the subsonic (“low pressure”) flow  Carbon monoxide   28            1.40       356
         formula is required. If so, then determine “F” factor. If not,  Ethane       30            1.19       336
         use above sonic flow formula.                          Ethylene               28            1.24       341
                                                               Freon 22               86.47         1.18       335
                   QGI                                         Helium                  4            1.66       377
          A =                                                  Hexane                 86            1.06       322
             863 KF ( 1  P 2  P 2                              Hydrogen                2            1.41       357
                     P - ) ¥
                                                               Hydrogen sulfide        34            1.32       349
         where: G = Specific gravity                            Methane                16            1.31       348
                 F = Factor obtained from Table 1              Methyl mercapton       48.11         1.20       337
                P 2 = Outlet pressure, psia (backpressure  + atmos.   N-Butane        58            1.09       326
                    pres.)                                     Natural gas (0.60)     17.4          1.27       344
                                                               Nitrogen               28            1.40       356
           After determining the calculated orifice area, select the  Oxygen           32            1.40       356
         next largest standard orifice size from the relief valve manu-  Pentane       72            1.07       323
                                                               Propane                44            1.13       330
         facturer’s catalog.
                                                               Propylene              42            1.15       332
                                                               Sulfur dioxide         64            1.29       346
                                                               VCM                    62.5          1.18       335
                              Selection

           The fundamental selection involves the consideration of
         the two basic types of relief valves more commonly used; con-
         ventional spring-loaded type and pilot operated relief valves.
           Advantages of the spring-loaded relief valves are:

           • Competitive price at lower pressures and in smaller sizes
           • Wide range of chemical compatibility
           • Wide range of temperature compatibility, particularly at
             higher temperatures.

           The disadvantages are:                                  Figure 2. Setting seat pressure to set flow pressure.

           • Metal-to-metal seat not tight near set pressure and  • Can achieve short blowdown without chatter
             usually after valve relieves                        • Pop or modulating action available
           • Sensitive to conditions that can cause chatter and/or  • Easy maintenance
             rapid cycling                                       • Easy verification of set pressure without removing relief
           • Protection against effects of backpressure is expensive,  valve from service
             pressure limited, and creates possible, additional main-  • Flexible—options for remote operation, backpressure
             tenance problems                                      protection, valve position indication.
           • Testing of set pressure not easily accomplished.
                                                                 The disadvantages are:
           Advantages of pilot operated type relief valves are:
                                                                 • Maximum temperature limitations
           • Seat tight to set pressure (Fig. 2)                 • Should not be used in extremely dirty or polymerizing
           • Ease of setting and changing set and blowdown pressures  type service.
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