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                        TABLE 32.1
                        120 BOD Observations Made at 2-h Intervals
                                                           Sampling Interval
                         Day    1     2     3     4     5     6     7     8     9    10    11    12
                          1    200   122   153   176   129   168   165   119   113   110   113    98
                          2    180   122   156   185   163   177   194   149   119   135   113   129
                          3    160   105   127   162   132   184   169   160   115   105   102   114
                          4    112   148   217   193   208   196   114   138   118   126   112   117
                          5    180   160   151    88   118   129   124   115   132   190   198   112
                          6    132    99   117   164   141   186   137   134   120   144   114   101
                          7    140   120   182   198   171   170   155   165   131   126   104    86
                          8    114    83   107   162   140   159   143   129   117   114   123   102
                          9    144   143   140   179   174   164   188   107   140   132   107   119
                         10    156   116   179   189   204   171   141   123   117    98    98   108
                        Note: Time runs left to right.


                                           250
                                          BOD (mg/L)  200

                                           150
                                           100
                                            50
                                              0  24  48  72  96  120  144  168  192  216  240
                                                              Hours

                       FIGURE 32.1 A record of influent BOD data sampled at 2-h intervals.

                        The correlation coefficients of the lagged observations are called autocorrelation coefficients, denoted
                       as ρ k . These are estimated by the lag k sample autocorrelation coefficient as:
                                                           (
                                                                (
                                                     r k =  ∑ y t –  y) y t−k – y)
                                                         --------------------------------------------
                                                            ∑ y t –(  y)  2
                       Usually the autocorrelation coefficients are calculated for k  = 1 up to perhaps n/4, where n is the length
                       of the time series. A series of n ≥ 50 is needed to get reliable estimates. This set of coefficients (r k ) is
                       called the autocorrelation function (ACF). It is common to graph r k  as a function of lag k. Notice that
                       the correlation of y t  with y t  is r 0  = 1. In general, −1 < r k  < +1.
                        If the data vary about a fixed level, the r k  die away to small values after a few lags. The approximate
                       95% confidence interval for r k  is ±1.96/ n . The confidence interval will be ±0.28 for n = 50, or less for
                       longer series. Any r k  smaller than this is attributed to random variation and is disregarded.
                        If the r k  do not die away, the time series has a persistent trend (upward or downward), or the series
                       slowly drifts up and down. These kinds of time series are fairly common. The shape of the autocorrelation
                       function is used to identify the form of the time series model that describes the data. This will be
                       considered in Chapter 51.



                       Case Study Solution
                       Figure 32.2 shows plots of BOD at time t, denoted as BOD t , against the BOD at 1, 3, 6, and 12 sampling
                       intervals earlier. The sampling interval is 2 h so the time intervals between these observations are 2, 6,
                       12, and 24 h.

                       © 2002 By CRC Press LLC
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