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L1592_frame_C35  Page 317  Tuesday, December 18, 2001  2:52 PM











                                             10.0         0.22        0.22       0.22
                                             20.0         0.51        0.51       0.51
                                             40.0          —          0.48       0.48
                                             50.0          —          0.29       0.29
                                             60.0          —          0.20       0.20
                                             70.0          —          0.12       0.12

                            For each experiment, use nonlinear least squares to (a) estimate the two parameters in the
                            model, (b) plot the predicted and observed concentrations of B vs. time, (c) plot the residuals
                            vs. time and vs. the predicted concentration of B, and (d) plot the approximate 95% joint
                            confidence region for the estimated parameters. Discuss the difference between the result
                            obtained for the three experiments.
                       35.8  Modeling. Discuss two environmental engineering systems that are described by the model
                            in Exercise 35.7. The systems may be natural or constructed. Optional: Find some data for
                            one of the systems and analyze it.
                       35.9  Chick’s Law. The table below gives some data on fraction (F) of coliform bacteria surviving
                            for a given contact time (T, min.) at a given chlorine dosage (C, mg/L). The classical model
                            for bacterial die-off is Chick’s law: ln(F) = −kCT, so this might be a starting model. An
                                                     a
                            alternate model is ln(F ) = −bTC . Which model is best?
                                                                 Chlorine Dosage (mg/L)
                                     Contact Time (min)  1 mg/L  2 mg/L    4 mg/L     8 mg/L
                                            0           1.000     1.000     1.000     1.000
                                           15           0.690     0.280     0.400     0.200
                                           30           0.400     0.110     0.090     0.0390
                                           45           0.250     0.090     0.032     0.0075
                                           60           0.150     0.0320    0.008     0.0012
                                           75           0.080     0.0080    0.0016    0.0003
                                           90           0.050     0.0045    0.0009    0.00005
                                     Source: Tikhe, M. L. (1976). J. Envir. Engr. Div., ASCE, 102, 1019–1028.




































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