Page 213 - Basic physical chemistry for the atmospheric sciences
P. 213
Index ( IJI)
mass, SI unit of, 1 5 7 molecular weight(s)
mass balance, charge balance relations apparent
and, 97-98 of dry air, 70
mass balance relation, definition of, 98 of a solution, 70
mega (prefix). definition and symbol for, derivation of, 2
1 5 7 molecules
2
mercuric ion [mercury (II); Hg + ] , 1 7 2 collision of, 52-55, 66
thermodynamic properties of, 1 70 configuration of, potential energy based
mercurous ion [mercury (!); Hg� + ] , 1 7 2 on, 1 7
thermodynamic properties of, 1 7 0 kinetic energies of, 54
mercury (Hg) in I mole, 2
atomic weight of, 1 6 0 motion of, internal kinetic energy based
thermodynamic properties of, 1 7 0 on, 17
mercury (I) chloride (Hg2Cl2), solubility monoatomic substances, oxidation num
(or ion) product constant for, 167 bers for, 1 06
mercury gas (Hg), thermodynamic proper monohydrogen phosphate ion (HPo�- ).
ties of, 1 7 0 1 7 2
mercury (II) sulfide (HgS), solubility (or equilibrium (or dissociation) constant
ion) product constant for, 167 for, 163
mesosphere, ozone formation in, 3 Mt. Pinatubo (Philippines), sulfur dioxide
metal complex ions, formation constants release from eruption of 1 99 1 ) , 1 5 5
(
of, 97 multiple proportions, law of, 1 2
metal ions, as Lewis acids, %
metal oxides, as heterogenous catalysts,
58 N
metals, as heterogenous catalysts, 58 nano (prefix), definition and symbol for,
methane (CH4) 1 5 7
atmospheric composition of, 6 natural systems, chemical residence time
atomic chlorine reaction with, in strato in, 60-6 1
natural waters, pH values of, 89
sphere, 1 5 1
thermodynamic properties of, 1 6 9 Nernst equation, 1 2 6- 1 2 8
micro (prefix), definition and symbol for, use to derive electric potential differ-
-
1 5 7 ence, 1 2 6 1 2 8
milli (prefix), definition and symbol for, neutralization, of acids and bases, 84
1 5 7 neutral solution, definition of, 83
mol . See mole newton, definition and symbol for, 1 5 7
molal boiling-point-elevation constant, 72 nickel (II) sulfide (NiS), solubility (or ion)
molal concentration , of a solution, 69 product constant for, 1 6 7
molal freezing-point-depression constant, nitramide (0 NNH2), decomposition reac
2
72 tions of, 64
molality, of a solution, 69 nitrate ion (N03), 1 7 2
molar concentration, of a solution , 69 thermodynamic properties of, 170
molar heat of formation. See molar stan- nitric acid (HN03), 84
dard enthalpy (or heat) of formation equilibrium (or dissociation) constant
molarity for, 162
definition of, 4 formation from nitrogen oxides (NOy),
of a solution, 69 15 1
molar standard enthalpy (or heat) of for in ice-water particles of polar strato
2
mation, 1 , 22, 1 6 9 - 1 7 1 , 1 7 6 spheric clouds, 1 5 1
molar standard enthalpy (or heal) of reac oxidation-reduction reaction with hy
tion, 2 1 drogen sulfide, 1 0 7, 108, I 09- 1 1 1
molar standard free energy change, defi in polluted rainwater, 1 00
nition of, 30 a s strong acid , 88
molar standard Gibbs free energy of for nitric acid trihydrate (HN03·3H20) parti
matio , 30, 169- 1 7 1 cles, in polar stratospheric clouds,
n
mole, definition of, 2 1 5 1
