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218                           Principles of semiconductor devices



                                                             Silicon substrate
                                                        Electrode Spacer


     Fig. 9.59
                                                                          Oxide
     Schematic representation of a
     quadrupole filter in a mass                             Groove
     spectrometer.                                      Ion beam

                                   to chemical etches. Hence etching through rectangular mask openings cre-
                                   ates V-shaped grooves, which can locate two electrodes. Next the silicon is
                                   thermally oxidized to provide a surface oxide layer. This is necessary because
                                   the electrodes must be insulated. The whole assembly of the quadrupole filter
                                   (Fig. 9.59) can then be constructed from two dies, each carrying two electrodes
                                   and separated by cylindrical spacers in similar grooves.
                                     And now we have come to the most interesting question: how large is a
                                   mass spectrometer? Those designed by the founding fathers needed a good-
                                   sized room to accommodate them. How large is this miniaturized version? The
                                                                                           3
                                   major item is the filter, which has dimensions of about 6 × 3 × 30 mm , con-
                                   siderably below the size of a room. A complete mass spectrometer of course
                                   needs an ion source, an ion detector, a vacuum enclosure, vacuum pumps, and
                                   drive electronics. There is some way to go before all of these components are
                                   miniaturized. However, as unlikely as it seems, desk-top mass spectrometers
                                   containing MEMS quadrupole mass filters, together with other MEMS devices
                                   (an electrospray ion source operating at atmospheric pressure and a chip that al-
                                   lows ions to be transported into the vacuum system) are already commercially
                                   available.


                                   9.27  Nanoelectronics

                                   We are getting more familiar with devices and techniques in the nanometre
                                   region. At the time of writing (August 2013), transistors with a minimum fea-
                                   ture size of 32 nm are available commercially. There is, however, still an aura of
                                   mystery surrounding the subject. This is partly due to some exaggerated claims
                                   made in the past decade by science fiction writers aided and abetted by some
                                   scientists. It is the dream of nanobots, little robots that will do everything con-
                                   ceivable: producing food from basic elements and, when needed, scrambling up
                                   in your veins in order to repair a clot. A further reason might be the awe we all
                                   feel when coming to atomic dimensions. Can we really interfere so much with
                                   nature? Will nature fight back? The third reason is that, apart from brute force
                                   (as manifested in the continual reduction in the size of traditional devices),
                                   nobody is sure in what direction to push ahead; or, rather, every participant in
                                   the game, which is amply financed, is pushing ahead in a different direction.
                                     By the nature of the problem there are two basic approaches: top-down
                                   and bottom-up. In the former case one proceeds like a sculptor chiselling
                                   away unwanted material and adding bits here and there. This is the approach
                                   of microelectronics, the familiar approach. The bottom-up approach is the
                                   new one. It can be done. It is not impossible, just pretty difficult. Let me
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