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Osiander / MEMS and microstructures in Aerospace applications DK3181_c003 Final Proof page 43  1.9.2005 8:59pm




                    MEMS Fabrication                                                 43



                          TABLE 3.2
                          Common Crystalline Silicon Etchants’ Selectivity and Etch Rates
                          Etchant                                     Etch Rate
                          18HF þ 4HNO 3 þ 3Si ! 2H 2 SiF 6 þ 4NO þ 8H 2 O  Nonselective
                                                                   {1 0 0} 0.14 m/min
                          Si þ H 2 O þ 2KOH ! K 2 SiO 3 þ 2H 2
                                                                   {1 1 1} 0.0035 m/min
                                                                   SiO 2 0.0014 m/min
                                                                   SiN 4 not etched
                          Ethylene diamine pyrocatechol (EDP)      {1 0 0} 0.75 m/min
                                                                   {1 1 1} 0.021 m/min
                                                                   SiO 2 0.0002 m/min
                                                                   SiN 4 0.0001 m/min
                          Tetramethylammonium hydroxide (TMAH)     {100} 1.0 m/min
                                                                   {1 1 1} 0.029 m/min
                                                                   SiO 2 0.0002 m/min
                                                                   SiN 4 0.0001 m/min


                                    BBBBBBBBBBBBBBBBBBBBBBBB





                                                   Single Crystal Silicon


                                         (a)  Implant Boron in Single Crystal Silicon wafer

                          SiO  Mask                    <100>
                            2


                                    BBBBBBBBBBBBBBBBBBBBBBBB



                                        (b)  Deposit and Pattern Silicon Dioxide Etch Mask




                                                     <111>
                                    BBBBBBBBBBBBBBBBBBBBBBBB



                                                     (c)  KOH Etch
                    FIGURE 3.5 Boron-doped silicon used to form features or an etch stop.




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