Page 283 - Sami Franssila Introduction to Microfabrication
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262 Introduction to Microfabrication











                                        (a)                          (b)






                                        (c)                          (d)
            Figure 25.5 Shallow trench isolation, STI: (a) trench etching with a oxide/nitride stack followed by liner thermal
            oxidation; (b) CVD oxide deposition; (c) CMP polishing until nitride stop layer and (d) nitride and oxide etching


            isolation method in the deep sub-micron technologies is  is higher, planarization will only work for the narrow
            STI. The process starts very much like recessed LOCOS,  gaps. Instead of CMP, various etchback processes have
            but then it takes advantage of CMP, which offers pla-  also been tried, but they have pattern size and pattern
            narity of the final structure. A schematic STI process is  density effects similar or worse than CMP, and the
            described below.                             results are therefore no better.


            Process flow for shallow trench isolation (STI)  25.4 GATE MODULE
            pad oxide (thermal)                          Gate module is critical for transistor action. Gate oxide
            pad nitride (LPCVD)                          thickness, channel doping, gate length and source/drain
            lithography                                  doping profiles determine critical transistor parameters
            etching nitride/oxide/silicon (isolation depth determined  such as threshold voltage, switching speed, leakage
              by etched silicon depth)                   current and noise. current and noise. The MOS gate
            resist strip and cleaning                    module is very critical with respect to cleaning: as shown
            liner oxidation to form a high-quality silicon/oxide  in Table 25.7 there are numerous contamination effects.
              interface
            CVD oxide deposition (trench overfilling)     25.4.1 Gate oxide
            CMP planarization of the oxide, polish stop at nitride
            etch pad nitride                             Making thin gate oxides is a major wafer cleaning
            etch pad oxide.                              challenge: 100 nm particles are permissible in 0.35 µm
                                                         technology from a linewidth point of view, but compared
              Note that Figure 25.5 is drawn to scale in x, y and z.  to <10 nm oxide thicknesses they are not allowed.
                                                         Atomic contamination also becomes more crucial as film
             – pad oxide 40 nm
             – pad nitride 100 nm                        Table 25.7 Metal contamination effects in MOS devices.
                                                         Adapted from ref. Hattori
             – narrow trench width 250 nm
             – trench depth 300 nm                       Metallic species   Contamination effects in MOS
             – liner oxide 30 nm
             – CVD oxide 500 nm                          Heavy metals       Junction leakage current
                                                          (Cu, Fe, Ni)       increase
                                                                            Lifetime degradation
            There are tens of variations of STI, but all of them have
                                                                            Oxide dielectric strength failure
            to fulfil certain common criteria. Overfill has to fill not
                                                         Alkali metals      Threshold voltage shift
            only narrow trenches but also larger areas (of course,
                                                          (Na, K, Ca, . . .)
            there can be a design rule limitation on trench widths).
                                                         Transition metals (Al)  Interface state increase
            CMP planarization has also to be able to polish narrow  Noble metals (Au)  Lifetime degradation
            and large areas at the same rate. If a large area polish rate
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