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4.4 Fabrication  151
                             2. a Si-based negative resist with high resistance to oxygen reactive ion-beam
                               etching(O 2 RIE) is spin-coated onto the polyimide layer and exposed to
                               an electron beam
                             3. the polyimide layer is etched down to the Si substrate by O 2 RIE
                             4. after removal of the resist, the microrotor are freed from the substrate by
                               ultrasonic vibration.
                            Fluorinated polyimide has a density of 1.49 and a refractive index of 1.53 at
                            a wavelength of 1.064 µm as listed in Table 3.3.

                            4.4.2 Microphotoforming

                            In order to increase the optical torque of the rotor, it is effective to adopt a 3-D
                            structure with slopes on its upper surface. To fabricate such 3-D microstruc-
                            tures, photoformingis applied. However, the presently proposed photoforming
                            apparatus is large and requires a special laser beam (ultra-short-pulsed near-
                            infrared Ti:sapphire)or special resin (two-photon-absorbed urethane material)
                            [1.29, 4.17].
                               We developed a desktop microphotoformingapparatus usinga DVD opti-
                            cal head and a visible light-curable resin (DF-200N, Nippon Kayaku Corp.),
                            both of which are commercially available [4.18]. Since the microstructure is
                            generated by scanning a focused laser beam to solidify the contour of a liq-
                            uid photopolymer, the resolution is determined by the laser beam intensity
                            distribution and the absorption of light within the polymer. To decrease the
                            solidified depth, a thin resin film was made usinga spinner, as shown in
                            Fig. 4.44
                               Figure 4.45 shows the shuttlecock optical rotor with a 30 µm diameter and
                            15 µm thickness. The fabrication conditions were a scan speed of 25 µms −1 ,
                            scan pitch of 0.3 µm, single scan and a laser power of 0.35 mW. The overall
                            time was 12 min to fabricate 16 rotors.

                            (a)                                 (b)
                               Z stage       Optical head


                                                                              Z stage
                                                       Resin
                                           Spinner                     Optical head      Resin
                                                                                        Spinner
                                                            PC
                                                                           X stage
                                           XY stage
                                                                               Y stage

                            Fig. 4.44. Schematic diagram (a), and photograph (b)of the spinner-type mi-
                            crophotoforming apparatus
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