Page 177 - Microsensors, MEMS and Smart Devices - Gardner Varadhan and Awadelkarim
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      1.  Polyimide has  a  small  elastic  modulus, which  is  about  50  times  smaller  than  that of
        polycrystalline  silicon.
      2.  Polyimide can  take  large  strains  before  fracture.
      3.  Both  polyimide  and  aluminum  can  be  prepared  at  relatively  low  temperatures
        (<400°C).

      However,  the  main  disadvantage  of  this  material  system  lies  with  polyimide  in  that  it
      has  unfavourable  viscoelastic  characteristics  (i.e.  it  tends  to  creep),  and  so  devices  may
      exhibit  considerable parametric  drift.


      6.3.3  Silicon  Nitride/Polycrystalline  Silicon  and
            Tungsten/Silicon  Dioxide

      In  the  third  material  system of  silicon  nitride/poly-Si,  silicon  nitride  is  used  as  the struc-
      tural  material  and  poly-Si  as  the  sacrificial  material.  For  this  material  system,  silicon
      anisotropic  etchants such  as potassium  hydroxide  (KOH)  and  ethylenediarnine pyrocate-
                                          9
      chol  (EDP)  are used to  dissolve  the  poly-Si .
        In the  fourth  material  system  of tungsten/oxide,  tungsten deposited by CVD is used as
      the  structural  material  with the  oxide  as the  sacrificial material.  Here  again,  HF  solution
      is  used  to remove  the  sacrificial  oxide.
        Finally, we give a worked  example  in which silicon nitride is employed  as the structural
      material  as before but as a variant and, unusually, aluminum is used as the sacrificial  layer
      instead  of poly-Si.


        Worked  Example  E6.5:  Silicon Condenser  Microphone 10

        Objective:
        The objective  is to fabricate  a silicon condenser  microphone  using silicon  nitride  as the
        structural  layer and aluminum as the  sacrificial  layer. In this case,  gold  is used  to make
        the electrical tracks.
        Process Flow:

        1.  First,  the  backside  and polished front  side  of a silicon  wafer are covered with  1.8 jim
          and  0.45  |um thermal  oxides,  respectively.  A  square  window  is  then  etched  on  the
          oxide  on  the  backside.  A  sacrificial  layer  of  aluminum  about  1.0 urn  thick  is  then
          evaporated  onto  the  polished  front  side  of  the  wafer  and  patterned,  followed  by
          plasma-enhanced  chemical  vapour  deposition  (PECVD)  of  1.3 urn of  silicon  nitride
          (Figure  6.11 (a)).
        2.  The diaphragm-to-be silicon  nitride film is provided  with  a 30 nm titanium  adhesion
          layer and a 30-nm gold electrode.  Holes and V-grooves are then etched anisotropically
          from  the  backside  using  KOH,  and  the  KOH  etch  stops  at  the  SiO2 etch-stop layer
          (Figure 6.1 l(b)).

      9
       Details of  these etches  are given in Section  2.4.
      10
        For details  see Scheeper  et al.  (1992).
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